Improving surface passivation on very thin substrates for high efficiency silicon heterojunction solar cells

被引:25
|
作者
Balaji, Pradeep [1 ]
Dauksher, William J. [1 ]
Bowden, Stuart G. [1 ]
Augusto, Andre [1 ]
机构
[1] Arizona State Univ, Solar Power Lab, Tempe, AZ 85284 USA
基金
美国国家科学基金会;
关键词
Silicon; Thin PV cells; Heterojunction solar cells; Surface passivation; Open circuit voltage; Saturation current density; QUANTIFICATION; LOSSES; PECVD; FILMS;
D O I
10.1016/j.solmat.2020.110715
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Silicon solar cells are now less than 3% absolute from the theoretical efficiency limit. Advanced passivated contact architectures have demonstrated surface saturation current densities close to 1 fA/cm(2). We have optimized the thin intrinsic hydrogenated amorphous silicon layer by controlling the deposition temperature and the silane-to-hydrogen dilution ratio. Thin wafers were used as a testbed to increase the sensitivity to surface passivation. By optimizing the intrinsic layer, we reduced the surface saturation current densities from 1.7 fA/cm(2) to 0.6 fA/cm(2) on textured wafers with thicknesses ranging between 40 and 180 mu m. Implied open-circuit voltages over 760 mV were accomplished on p-i/c-Si/i-n structures deposited on n-type CZ wafers with wafer thicknesses below 50 mu m. Further, we demonstrated experimentally the potential of using very thin wafers by manufacturing screen-printed silicon heterojunction solar cells on 40 mu m thick standalone wafers while achieving an efficiency of 20.48%.
引用
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页数:8
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