Small Molecules, Non-Covalent Interactions, and Confinement

被引:35
作者
Buntkowsky, Gerd [1 ]
Vogel, Michael [2 ]
机构
[1] Tech Univ Darmstadt, Inst Phys Chem, D-64287 Darmstadt, Germany
[2] Tech Univ Darmstadt, Inst Festkorperphys, D-64295 Darmstadt, Germany
关键词
confinement; solid-state NMR; molecular dynamics; interfaces and surfaces; SOLID-STATE NMR; DYNAMIC NUCLEAR-POLARIZATION; ORGANIC FUNCTIONAL-GROUPS; MESOPOROUS SILICA MCM-41; HYDROGEN-BONDED LIQUIDS; SPIN-LATTICE-RELAXATION; GUEST-HOST INTERACTIONS; IONIC LIQUIDS; WATER-MOLECULES; HIGH-RESOLUTION;
D O I
10.3390/molecules25143311
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
This review gives an overview of current trends in the investigation of small guest molecules, confined in neat and functionalized mesoporous silica materials by a combination of solid-state NMR and relaxometry with other physico-chemical techniques. The reported guest molecules are water, small alcohols, and carbonic acids, small aromatic and heteroaromatic molecules, ionic liquids, and surfactants. They are taken as characteristic role-models, which are representatives for the typical classes of organic molecules. It is shown that this combination delivers unique insights into the structure, arrangement, dynamics, guest-host interactions, and the binding sites in these confined systems, and is probably the most powerful analytical technique to probe these systems.
引用
收藏
页数:32
相关论文
共 274 条
[91]  
2-1
[92]   Local Microphase Separation of a Binary Liquid under Nanoscale Confinement [J].
Guo, Xiang-Yang ;
Watermann, Tobias ;
Sebastiani, Daniel .
JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (34) :10207-10213
[93]   Mutable Lewis and Bronsted Acidity of Aluminated SBA-15 as Revealed by NMR of Adsorbed Pyridine-15N [J].
Gurinov, Andrey A. ;
Rozhkova, Yulia A. ;
Zukal, Arnost ;
Cejka, Jiri ;
Shenderovich, Ilya G. .
LANGMUIR, 2011, 27 (19) :12115-12123
[94]   Solid-state NMR of nanocrystals [J].
Gutmann, Torsten ;
Groszewicz, Pedro B. ;
Buntkowsky, Gerd .
ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 97, 2019, 97 :1-82
[95]   31P-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts [J].
Gutmann, Torsten ;
Alkhagani, Safaa ;
Rothermel, Niels ;
Limbach, Hans-Heinrich ;
Breitzke, Hergen ;
Buntkowsky, Gerd .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2017, 231 (03) :653-669
[96]   Solid-state NMR concepts for the investigation of supported transition metal catalysts and nanoparticles [J].
Gutmann, Torsten ;
Gruenberg, Anna ;
Rothermel, Niels ;
Werner, Mayke ;
Srour, Mohamad ;
Abdulhussain, Safaa ;
Tan, Shulin ;
Xu, Yeping ;
Breitzke, Hergen ;
Buntkowsky, Gerd .
SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2013, 55-56 :1-11
[97]   Understanding the leaching properties of heterogenized catalysts: A combined solid-state and PHIP NMR study [J].
Gutmann, Torsten ;
Ratajczyk, Tomasz ;
Xu, Yeping ;
Breitzke, Hergen ;
Gruenberg, Anna ;
Dillenberger, Sonja ;
Bommerich, Ute ;
Trantzschel, Thomas ;
Bernarding, Johannes ;
Buntkowsky, Gerd .
SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2010, 38 (04) :90-96
[98]   On the problem of field-gradient NMR measurements of intracrystalline diffusion in small crystallites - Water in NaA zeolites as an example [J].
Gutsze, A ;
Masierak, W ;
Geil, B ;
Kruk, D ;
Pahlke, H ;
Fujara, F .
SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2005, 28 (2-4) :244-249
[99]   A novel route to highly porous bioactive silica gels [J].
Hall, SR ;
Walsh, D ;
Green, D ;
Oreffo, R ;
Mann, S .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (02) :186-190
[100]  
Haouas M., 2007, QUADRUPOLAR NMR NANO