Characterization of the waxes obtained by the pyrolysis of polyolefin plastics in a conical spouted bed reactor

被引：211
作者：
Arabiourrutia, M. [1 ]
Elordi, G. [1 ]
Lopez, G. [1 ]
Borsella, E. [1 ]
Bilbao, J. [1 ]
Olazar, M. [1 ]
机构：
[1] Univ Basque Country, Dept Chem Engn, E-48080 Bilbao, Spain
来源：
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2012年 / 94卷
关键词：
Waxes; Plastic pyrolysis; Conical spouted bed reactor; HIGH-DENSITY POLYETHYLENE; CATALYTIC DEGRADATION; PRODUCT DISTRIBUTION; VACUUM PYROLYSIS; POLYPROPYLENE; WASTE; HZSM-5; CONVERSION; OPERATION; MIXTURES;
D O I：
10.1016/j.jaap.2011.12.012
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The thermal pyrolysis of three different polyolefin plastics (HDPE, LOPE and PP) has been carried out in a conical spouted bed reactor. This technology is especially interesting because of the high selectivity to waxes due to the low residence times and high heating rates that reduce secondary reactions and increase the yield of primary pyrolysis products (waxes). These have been obtained operating at 450, 500 and 600 degrees C and a complete characterization has been carried out using different techniques, such as gel permeation chromatography (GPC), Fourier transform infrared (FTIR) spectrophotometry, simulated distillation and the measurement of heating value and melting point. Operating conditions and feed type have been observed to have a significant effect on the properties of the different waxes. The characterization has been carried out bearing in mind the potential use of waste plastic-derived waxes as a feedstock for cracking units. (C) 2011 Elsevier B.V. All rights reserved.
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页码：230 / 237
页数：8
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