Calcium oxide supported gold nanoparticles as catalysts for the selective epoxidation of styrene by t-butyl hydroperoxide

被引：41

作者：

Dumbre, Deepa K. ^{[2
]}

Choudhary, Vasant R. ^{[1
]}

Patil, Nilesh S. ^{[1
]}

Uphade, Balu S. ^{[1
]}

Bhargava, Suresh K. ^{[2
]}

机构：

[1] Natl Chem Lab, Chem Engn & Proc Dev Div, Pune 411008, Maharashtra, India

[2] RMIT Univ, Ctr Adv Mat & Ind Chem, Sch Appl Sci, Melbourne, Vic, Australia

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2014年 / 415卷

关键词：

Epoxidation of styrene; Styrene oxide; Gold nanoparticles; Au/CaO; Homogenous deposition precipitation method; SOLVENT-FREE OXIDATION; VAPOR-PHASE EPOXIDATION; HIGHLY-ACTIVE CATALYST; BENZYL ALCOHOL; NANO-GOLD; MOLECULAR-OXYGEN; BENZALDEHYDE; TS-1; HYDROGEN; WATER;

D O I：

10.1016/j.jcis.2013.10.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gold nanoparticles are deposited on basic CaO supports as catalysts for the selective conversion of styrene into styrene oxide. Synthetic methods, gold loading and calcination temperatures are varied to permit an understanding of their influence on gold nanoparticle size, the presence of cationic gold species and the nature of interaction between the gold nanoparticles and the CaO support. Based on these studies, optimal conditions are designed to make the Au/CaO catalyst efficient for the selective epoxidation of styrene. (C) 2013 Elsevier Inc. All rights reserved.

引用

页码：111 / 116

页数：6

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