Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells

被引：106

作者：

Long, Brandon R. ^{[1
]}

Rinaldo, Steven G. ^{[1
]}

Gallagher, Kevin G. ^{[1
]}

Dees, Dennis W. ^{[1
]}

Trask, Stephen E. ^{[1
]}

Polzin, Bryant J. ^{[1
]}

Jansen, Andrew N. ^{[1
]}

Abraham, Daniel P. ^{[1
]}

Bloom, Ira ^{[1
]}

Bareno, Javier ^{[1
]}

Croyz, Jason R. ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2016年 / 163卷 / 14期

关键词：

HIGH-POWER; BATTERIES; ELECTRODE;

D O I：

10.1149/2.0691614jes

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Coin-cells are often the test format of choice for laboratories engaged in battery research and development as they provide a convenient platform for rapid testing of new materials on a small scale. However, reliable, reproducible data via the coin-cell format is inherently difficult, particularly in the full-cell configuration. In addition, statistical evaluation to prove the consistency and reliability of such data is often neglected. Herein we report on several studies aimed at formalizing physical process parameters and coin-cell construction related to full cells. Statistical analysis and performance benchmarking approaches are advocated as a means to more confidently track changes in cell performance. We show that trends in the electrochemical data obtained from coin-cells can be reliable and informative when standardized approaches are implemented in a consistent manner. (C) 2016 The Electrochemical Society. All rights reserved.

引用

页码：A2999 / A3009

页数：11

共 17 条

[11] Cycling Behavior of NCM523/Graphite Lithium-Ion Cells in the 3-4.4 V Range: Diagnostic Studies of Full Cells and Harvested Electrodes
Gilbert, James A.
Bareno, Javier
Spila, Timothy
Trask, Stephen E.
Miller, Dean J.
Polzin, Bryant J.
Jansen, Andrew N.
Abraham, Daniel P.
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (01) : A6054 - A6065
[12] Surface structure evolution of cathode materials for Li-ion batteries
Lyu, Yingchun
Liu, Yali
Gu, Lin
[J]. CHINESE PHYSICS B, 2016, 25 (01)
[13] A Guide to Li-Ion Coin-Cell Electrode Making for Academic Researchers
Marks, Thomas
Trussler, Simon
Smith, A. J.
Xiong, Deijun
Dahn, J. R.
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (01) : A51 - A57
[14] Comparative Studies of Hardware Corrosion at High Potentials in Coin-Type Cells with Non Aqueous Electrolytes
Sinha, Nupur Nikkan
Burns, J. C.
Sanderson, R. J.
Dahn, Jeff
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (12) : A1400 - A1403
[15] A High Precision Study of the Coulombic Efficiency of Li-Ion Batteries
Smith, A. J.
Burns, J. C.
Dahn, J. R.
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (12) : A177 - A179
[16] Electrical energy storage for transportation-approaching the limits of, and going beyond, lithium-ion batteries
Thackeray, Michael M.
Wolverton, Christopher
Isaacs, Eric D.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (07) : 7854 - 7863
[17] Lithium batteries and cathode materials
Whittingham, MS
[J]. CHEMICAL REVIEWS, 2004, 104 (10) : 4271 - 4301

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