Co3M2S2 (M = Sn, In) shandites as tellurium-free thermoelectrics

被引：30

作者：

Corps, Jack ^{[1
]}

Vaqueiro, Paz

Powell, Anthony V.

机构：

[1] Heriot Watt Univ, Inst Chem Sci, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 22期

关键词：

HALF-ANTIPEROVSKITES; PERFORMANCE; FIGURE; TEMPERATURE; ENHANCEMENT; EFFICIENCY; BICUSEO; MERIT; PBTE; PBS;

D O I：

10.1039/c3ta11264k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chemical substitution in Co3Sn2-xInxS2 (0 <= x <= 2) enables tuning of the Fermi level within narrow bands of Co d-states. This results in a compositionally induced double metal-semiconductor-metal transition and manipulation of the thermoelectric power factor. The maximum power factor (14 mu W cm(-1) K-2) is found for x = 0.85, which corresponds to ZT approximate to 0.2 at 300 K.

引用

页码：6553 / 6557

页数：5

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