Conductive transparent V2CTx (MXene) films

被引:151
作者
Ying, Guobing [1 ,3 ]
Kota, Sankalp [1 ]
Dillon, Andrew D. [2 ]
Fafarman, Aaron T. [2 ]
Barsoum, Michel W. [1 ]
机构
[1] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[2] Drexel Univ, Dept Chem & Biol Engn, Philadelphia, PA 19104 USA
[3] Hohai Univ, Dept Mat Sci & Engn, Nanjing 211100, Jiangsu, Peoples R China
基金
中国国家自然科学基金; 瑞典研究理事会;
关键词
MXene; Aqueous suspensions processing; Conductive; Transparent; Spincast films; Optical absorption coefficient; TRANSITION-METAL CARBIDES; CATION INTERCALATION; PHASES;
D O I
10.1016/j.flatc.2018.03.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To date, the vast majority of research on the emerging 2D material MXene has been conducted on Ti3C2Tx. Herein, we report the first study on the optoelectronic properties of V2CTx MXene, and its processing into flexible, transparent films. Films were prepared from aqueous colloidal suspensions produced using tetrabutylammonium hydroxide, TBAOH, as the dispersant. After annealing, the DC conductivities, sigma(dc), of the thicker filtered and thinner spin cast films were both 3250 +/- 100 S/cm. The optical absorption spectrum of 10 nm films was found to be free of distinct transitions throughout the 500 to 2700 nm range. The absorption coefficient at a wavelength of 550 nm was determined to be approximate to 1.22 +/- 0.05 x 10(5) cm(-1), which renders it more than twice as transparent as Ti-based MXenes. As a result, a common figure of merit for transparent conductors-of the ratio of the DC to optical conductivities-of 6.5 is calculated for the V2CTx films.
引用
收藏
页码:25 / 30
页数:6
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