Degradation process regulation of waste LCD panel to ensure the remain of indium in solid phase by hydrothermal reaction

被引:6
作者
Cao, Yue [1 ]
Li, Feng [1 ]
Li, Guangming [1 ]
Huang, Juwen [1 ]
Zhu, Haochen [1 ]
He, Wenzhi [1 ]
机构
[1] Tongji Univ, Coll Environm Sci & Engn, Shanghai Inst Pollut Control & Ecol Secur, State Key Lab Pollut Control & Resources Reuse, 1239 Siping Rd, Shanghai 200092, Peoples R China
关键词
Waste LCD panel; Hydrothermal reaction; Degradation of organic materials; Indium; POLYCYCLIC AROMATIC-HYDROCARBONS; LIQUID-CRYSTAL; RESOURCE RECOVERY; ORGANIC MATERIALS; ACETIC-ACID; SEPARATION; PYROLYSIS; GLASS; EMISSION; GALLIUM;
D O I
10.1016/j.jhazmat.2019.02.033
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The environmental risks and recycling potential of organic materials and indium of waste LCD panel has produced commercial value. It has been found that hydrothermal reaction can achieve an efficient and clean degradation of organic materials in a closed environment. However, as the degradation process occurs, the glass substrate is gradually exposed to the hydrothermal environment. Whether the metal indium is dissolved into the liquid phase and whether it affects product quality and the subsequent leaching process need to be discussed. In present study, simultaneous organic materials degradation and pretreatment of indium recycling was achieved due to the regulation of parameters. Effects of reaction temperature, reaction time, H2O2 supply and pH of the reaction solution on the transfer of indium in liquid and solid phase were investigated. The results showed that the degradation rate of the organic material reach 90% under the neutral condition of 300 degrees C of reaction temperature, 36 mL of water and 7.2 mL of H2O2 supply and 11 min of reaction time. This pretreatment method effectively realized the resource recovery of waste LCD panel and the outflow of metal indium was inhibited at the same time, thus further comprehensive recycling of resources could be prepared.
引用
收藏
页码:125 / 131
页数:7
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