Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units

被引:14
作者
Agirtas, Mehmet Salih [1 ]
机构
[1] Van Yuzuncu Yil Univ, Fac Sci, Dept Chem, TR-65080 Van, Turkey
关键词
synthesis; characterization; fluorescence; silicon phthalocyanine; aggregation; solubility; COPPER PHTHALOCYANINE; METALLOPHTHALOCYANINES; AGGREGATION; PERFORMANCE; DERIVATIVES; EFFICIENT;
D O I
10.1515/hc-2020-0113
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon phthalocyanine complex were conducted on the chloroform, dimethyl formamide, dimethyl sulfoxide and tetrahydrofuran solutions. The findings of the fluorescence studies demonstrated that the compound has fluorescence spectra in the different solvents. The effects of the substitution with axially bis-4-tritylphenoxy functionalized groups on these parameters were also compared with the previously synthesized axially disubstituted silicon phthalocyanines. These results proved that the compound has different fluorescence properties in the different solvents.
引用
收藏
页码:130 / 136
页数:7
相关论文
共 29 条
[1]   Highly soluble phthalocyanines with hexadeca tert-butyl substituents [J].
Agirtas, M. Salih .
DYES AND PIGMENTS, 2008, 79 (03) :247-251
[2]   Synthesis and characterization of novel symmetrical phthalocyanines substituted with four benzo[d] [1,3] dioxol-5-ylmethoxy groups [J].
Agirtas, M. Salih .
INORGANICA CHIMICA ACTA, 2007, 360 (07) :2499-2502
[3]   Synthesis, Aggregation Behavior, and Electronic Properties of some Metallophthalocyanines with 2-Isopropyl-5-methylphenoxy Substituents [J].
Agirtas, M. Salih ;
Karatas, Ceyhun ;
Gumus, Selcuk .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (07) :1334-1339
[4]   Synthesis, characterization, and electrochemical and electrical properties of novel mono and ball-type metallophthalocyanines with four 9,9-bis(4-hydroxyphenyl)fluorene [J].
Agirtas, M. Salih ;
Altindal, Ahmet ;
Salih, Bekir ;
Saydam, Sinan ;
Bekaroglu, Ozer .
DALTON TRANSACTIONS, 2011, 40 (13) :3315-3324
[5]   Synthesis of Tetra 3,4-dimethoxyphenethoxy Peripheral Substituted Metallophthalocyanines and Investigation of Some Properties [J].
Agirtas, Mehmet Salih ;
Solgun, Derya Gungordu ;
Ozdemir, Sadin ;
Izgi, Mehmet Sait .
CHEMISTRYSELECT, 2018, 3 (12) :3523-3528
[6]  
[Anonymous], 2013, Purification ofLaboratory Chemicals
[7]   Phthalocyanine-doped polystyrene fluorescent nanocomposite as a highly selective biosensor for quantitative determination of cancer antigen 125 [J].
Attia, M. S. ;
Ali, K. ;
El-Kemary, Maged ;
Darwish, W. M. .
TALANTA, 2019, 201 :185-193
[8]   Synthesis of water soluble axially disubstituted silicon (IV) phthalocyanines with alkyne & azide functionality [J].
Bandera, Yuriy ;
Burdette, Mary K. ;
Shetzline, Jamie A. ;
Jenkins, Ragini ;
Creager, Stephen E. ;
Foulger, Stephen H. .
DYES AND PIGMENTS, 2016, 125 :72-79
[9]   Synthesis of new axially-disubstituted silicon-phthalocyanine derivatives: optical and structural characterisation [J].
Barker, Carl A. ;
Findlay, Karen S. ;
Bettington, Sylvia ;
Batsanov, Andrei S. ;
Perepichka, Igor F. ;
Bryce, Martin R. ;
Beeby, Andrew .
TETRAHEDRON, 2006, 62 (40) :9433-9439
[10]   High-sensitive room-temperature NO2 sensor based on a soluble n-type phthalocyanine semiconductor [J].
Dong, Zhen ;
Kong, Xia ;
Wu, Yanling ;
Zhang, Jinfu ;
Chen, Yanli .
INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 77 :18-22