3,3'-[(1RS, 3SR)-2-Oxocyclohexane1,3-diyl] bis[(3RS, 3′SR)-3-hydroxyindolin-2-one] dihydrate: organic layers of R22 (8), R22 (16) and R66 (40) rings linked by tetrameric water aggregates

被引:3
作者
Becerra, Diana [1 ]
Insuasty, Braulio [1 ]
Cobo, Justo [2 ]
Glidewell, Christopher [3 ]
机构
[1] Univ Valle, Dept Quim, Cali 25360, Colombia
[2] Univ Jaen, Dept Quim Inorgan & Organ, Jaen 23071, Spain
[3] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
crystal structure; hydrogen bonding; cyclic water tetramers; POTENTIAL ANTITUMOR-ACTIVITY; PHENYLPHOSPHONIC ACID; 4,4'-SULFONYLDIPHENOL; 4,4'-THIODIPHENOL; PATTERNS; ADDUCTS; AGENTS;
D O I
10.1107/S0108270113020908
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The organic component of the title compound, C22H20-N2O5 center dot 2H(2)O, exhibits approximate but noncrystallographic mirror symmetry. The molecules of the organic component are linked by a combination of one O-H...O hydrogen bond and two N-H...O hydrogen bonds to form sheets containing R-2(2) (8), R-2 (2) (16) and R-6(6) (40) rings. These sheets are linked into a continuous three-dimensional framework structure by cyclic centrosymmetric R-4(2)(8) water tetramers. Comparisons are made with some simpler analogues.
引用
收藏
页码:1081 / +
页数:10
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