Synthesis and sintering of (Mg, Co, Ni, Cu, Zn)O entropy-stabilized oxides obtained by wet chemical methods

被引:154
作者
Biesuz, Mattia [1 ,2 ]
Spiridigliozzi, Luca [3 ]
Dell'Agli, Gianfranco [3 ]
Bortolotti, Mauro [1 ]
Sglavo, Vincenzo M. [1 ,2 ]
机构
[1] Univ Trento, Dept Ind Engn, Via Sommar 9, Trento, Italy
[2] INSTM, Res Unit Trento, Via G Giusti 9, I-50121 Florence, Italy
[3] Univ Cassino & Southern Lazio, Dept Civil & Mech Engn, Via Di Biasio 43, I-03043 Cassino, FR, Italy
关键词
Sintering - Hydrothermal synthesis - Temperature - Ceramic materials - Powders;
D O I
10.1007/s10853-018-2168-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Entropy-stabilized oxides represent a novel family of advanced ceramic materials with attractive functional properties. In this work, entropy-stabilized oxides, in the system (Mg, Co, Ni, Cu, Zn)O, were produced by co-precipitation and hydrothermal synthesis. Although TG/DTA and XRD analyses of as-synthetized powders point out complex thermal evolution, in both cases the desired single-phase rock salt solid solution was obtained after a proper thermal treatment. The dilatometric analysis points out the excellent sinterability of the obtained powders, which were successfully consolidated for the first time reaching nearly full density (similar to 7%) at relatively low temperature (1050 A degrees C).
引用
收藏
页码:8074 / 8085
页数:12
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