The Thermodynamic Aspect of Melting and Softening of Nanoparticles

被引：6
作者：
Bal'makov, M. D. [1 ]
机构：
[1] St Petersburg State Univ, Fac Chem, Staryi Petergof 198904, Russia
来源：
GLASS PHYSICS AND CHEMISTRY | 2008年 / 34卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1134/S1087659608050064
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The specific features of the energy spectrum of stationary quantum states responsible for the melting and softening of a polyatomic system are investigated. It follows from the first principles of the quantum mechanics and statistical physics that the melting temperature of small nanoparticles can exceed the melting temperature of a macroscopic sample of the same chemical composition. The dependence of the temperature range of the transition of the polyatomic system to a microscopically labile state on the number of atoms is determined.
引用
收藏
页码：559 / 568
页数：10
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