Hydrogen Embrittlement Evaluation of Micro Alloyed Steels by Means of J-Integral Curve

被引:16
作者
Cabrini, Marina [1 ,2 ,3 ]
Sinigaglia, Ennio [4 ]
Spinelli, Carlo [5 ]
Tarenzi, Marco [6 ]
Testa, Cristian [1 ,2 ,3 ]
Bolzoni, Fabio Maria [7 ]
机构
[1] Univ Bergamo, Dept Engn & Appl Sci, I-24044 Dalmine, BG, Italy
[2] INSTM Unita Ric Bergamo, I-24044 Dalmine, BG, Italy
[3] CSGI Unita Ric Bergamo, I-24044 Dalmine, BG, Italy
[4] Transitgas AG Zurich Ch, CH-8001 Zurich, Switzerland
[5] Eni SpA TECM, I-20097 San Donato Milanese, MI, Italy
[6] Snam SpA DIREZ TECN, I-20097 San Donato Milanese, MI, Italy
[7] G Natta Politecn Milano, Dipartimenti Chim Mat & Ingn Chim, I-20131 Milan, MI, Italy
关键词
hydrogen embrittlement; pipeline steel; mechanical fracture; cathodic protection; STRESS-CORROSION CRACKING; X100 PIPELINE STEEL; PLASTIC-DEFORMATION; TRAPPING EFFICIENCY; LOW-TEMPERATURE; STRENGTH; MICROSTRUCTURE; SUSCEPTIBILITY; DIFFUSION; TRANSPORT;
D O I
10.3390/ma12111843
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The aim of this work is the evaluation of the hydrogen effect on the J-integral parameter. It is well-known that the micro alloyed steels are affected by Hydrogen Embrittlement phenomena only when they are subjected at the same time to plastic deformation and hydrogen evolution at their surface. Previous works have pointed out the absence of Hydrogen Embrittlement effects on pipeline steels cathodically protected under static load conditions. On the contrary, in slow strain rate tests it is possible to observe the effect of the imposed potential and the strain rate on the hydrogen embrittlement steel behavior only after the necking of the specimens. J vs. a curves were measured on different pipeline steels in air and in aerated NaCl 3.5 g/L solution at free corrosion potential or under cathodic polarization at -1.05 and -2 V vs. SCE. The area under the J vs. a curves and the maximum crack propagation rate were taken into account. These parameters were compared with the ratio between the reduction of area in environment and in air obtained by slow strain rate test in the same environmental conditions and used to rank the different steels.
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页数:17
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