Crystal structure and spectra of trans-bis(propanone, 1-[2-hydroxyphenyl]oximato)palladium(II)

被引：17
作者：
Voutsas, GP [1 ]
Keramidas, KG [1 ]
LaliaKantouri, M [1 ]
机构：
[1] UNIV THESSALONIKI,FAC CHEM,GR-54006 THESSALONIKI,GREECE
来源：
POLYHEDRON | 1996年 / 15卷 / 01期
关键词：
D O I：
10.1016/0277-5387(95)00097-C
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound [Pd(ppox)(2)], (where ppox(-) denotes the anion of 2-hydroxy-propiophenoneoxime, C9H10NO2-), was prepared and investigated by means of structural and spectroscopic (IR and electronic) measurements. The electronic excitation spectra are consistent with a square-planar PdN2O2 chromophore. The structure was determined by single-crystal X-ray diffraction and consists of discrete Pd(ppox)(2) monomeric units. The Pd atom is in the equatorial plane bonded to two nitrogen atoms and two oxygen at distances of 1.979(3) and 1.970(2) Angstrom, respectively.
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页码：147 / 151
页数：5
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