Catalytic Aerobic Dehydrogenatin of N-Heterocycles by N-Hydoxyphthalimide

被引：26

作者：

Chen, Weidong ^{[1
]}

Tang, Hao ^{[1
]}

Wang, Weilin ^{[1
]}

Fu, Qiang ^{[2
]}

Luo, Junfei ^{[1
]}

机构：

[1] Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China

[2] Southwest Med Univ, Sch Pharm, Luzhou 610041, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 18期

关键词：

Aerobic dehydrogenation; N-heterocycles; N-hydroxyphthalimide; Indolines; Quinolines; ACCEPTORLESS DEHYDROGENATION; OXIDATIVE DEHYDROGENATION; NITROGEN-HETEROCYCLES; SELECTIVE INHIBITORS; EFFICIENT CATALYST; CARBONYL-COMPOUNDS; MOLECULAR-OXYGEN; SECONDARY-AMINES; CYCLIC AMINES; ALCOHOLS;

D O I：

10.1002/adsc.202000767

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Catalytic methods for the aerobic dehydrogenation ofN-heterocycles are reported. In most cases, indoles are accessed efficiently from indolines using catalyticN-hydroxyphthalimide (NHPI) as the sole additive under air. Further studies revealed an improved catalytic system of NHPI and copper for the preparation of other heteroaromatics, for example quinolines.

引用

页码：3905 / 3911

页数：7

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