Rhodium-catalyzed domino silylformylation of enynes involving carbocyclization

被引：22

作者：

Fukuta, Y ^{[1
]}

Matsuda, I ^{[1
]}

Itoh, K ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 25期

关键词：

carbonylation; carbocyclization; rhodium catalyst; silylrhodation;

D O I：

10.1016/S0040-4039(99)00849-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,6-Enyne derivatives readily react with a hydrosilane and carbon monoxide in the presence of a catalytic amount of a rhodium complex to give 5-membered ring products containing a silylmethylene group and a formylmethyl group on the adjacent carbon atoms. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4703 / 4706

页数：4

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