On the basis of behavioral event interview and literature research method, it was combined excellent competency for teacher with entrepreneurial competency for student excellent together. Then from the perspective of interaction of Logistics Internet Platform, it was construct competency model with double subjects, which has five dimensions of learning competency, open competency, innovation competency, collaborative competency and cognitive competency. The connotation of community of practice in the Logistics Internet Platform was defined, and its characteristics and deep interactive tools were analyzed. Multi-agent collaborative blended learning mode based on mobile cloud services was put forward on the basis of full integration about situational learning, mobile learning and ubiquitous learning after learning reflection and technical reflection. And blended learning activity based on mobile cloud service in Logistic Internet Platform is designed, which includes three types of learning services, such as mobile location service, interactive feedback service and decision support service. The research of this paper is beneficial to the breakthrough of single learning mode, accelerate the dynamic matching ability with the outside world, and improve the efficiency of interactive learning.