A Two-Fold Interpenetrated Coordination Framework with a Rare (3,6)-Connected loh1 Topology: Magnetic Properties and Photocatalytic Behavior

被引：130

作者：

Chen, Yong-Qiang

Liu, Sui-Jun

Li, Yun-Wu

Li, Guo-Rong

He, Kun-Huan

Qu, Yang-Kun

Hu, Tong-Liang

Bu, Xian-He ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2012年 / 12卷 / 11期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; LUMINESCENT PROPERTIES; RUTILE TOPOLOGY; POLYMERS; LIGAND; ACID; NET; NETWORKS; MOFS;

D O I：

10.1021/cg301010x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new manganese(II) coordination polymer, [Mn-2(L1)(4/3)(L2)(2)](n) (1) (L1 = 4'-(4-pyridyl)-4,2':6',4 ''-terpyridine, H(2)L2 = (4-phenyl)-2,6-bis(4-carboxyphenyl)pyridine), has been prepared and structurally characterized. Complex 1 is a 2-fold interpenetrated three-dimensional framework, which to our knowledge represents the first interpenetration example of coordination framework with unique (3,6) connected loh1 topology. Furthermore, the magnetic properties and photocatalytic activity have been investigated. As a result, complex 1 displays a weak antiferromagnetic interaction among the Mn(II) centers and good photocatalytic activity for the degradation of methyl orange solution under ultraviolet light irradiation.

引用

页码：5426 / 5431

页数：6

共 68 条

[1] A cubic (3,4)-connected net with large cavities in solvated [Cu-3(tpt)(4)](ClO4)(3) (tpt=2,4,6-tri(4-pyridyl)-1,3,5-triazine) [J].