Reactions of Unsaturated Ketones with Bis(trimethylsilyl) Hypophosphite

被引：3
|
作者：
Tatarinov, D. A. [1 ,2 ]
Kundina, M. V. [2 ]
Dobrynin, A. B. [1 ]
Mironov, V. F. [1 ,2 ]
机构：
[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Inst Organ & Phys Chem, Ul Akad Arbuzova 8, Kazan 420088, Tatarstan, Russia
[2] Kazan Volga Reg Fed Univ, Kazan, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
bis(trimethylsilyl) hypophosphite; mesityl oxide; methyl vinyl ketone; bis(3-oxobutyl)phosphinic acid; phosphorinane;
D O I：
10.1134/S1070363218010140
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bis(trimethylsilyl) hypophosphite reacts with unsaturated ketones (methyl vinyl ketone and mesityl oxide) to give, depending on the reaction conditions, 1: 1 or 1: 2 adducts after hydrolysis. It was found that the intramolecular cyclization of the 1: 2 reaction product with mesityl oxide, trimethylsilyl bis(2-methyl-4- oxopentan-2-yl)phosphinate, yields, after hydrolysis, a phosphorinane with exocyclic carbonyl and hydroxyl groups.
引用
收藏
页码：90 / 95
页数：6
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