Biphasic chlorination of iodoarenes to (dichloroiodo)arenes

被引：0
|
作者：
Krassowska-Swiebocka, B
Prokopienko, G
Skulski, L
机构：
[1] Med Acad Warsaw, Fac Pharm, Chair Organ Chem, PL-02097 Warsaw, Poland
[2] Med Acad Warsaw, Fac Pharm, Organ Chem Lab, PL-02097 Warsaw, Poland
来源：
SYNLETT | 1999年 / 09期
关键词：
biphasic chlorination; (dichloroiodo)arenes; iodoarenes; organic hypervalent iodine reagents;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A two-phase (CCl4 / cone. hydrochloric acid) chlorination of some iodoarenes to the corresponding (dichloroiodo)arenes, prepared in 50-98% crude yields, is reported. Dichlorine is produced in the aqueous phase as follows: KClO3 (solid) + 6 HCl (conc. aq.) --> up arrow 3Cl(2) + KCl + 3H(2)O.
引用
收藏
页码：1409 / 1410
页数：2
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