Colloidal suspensions of N-modified graphene nano-platelets in water and organic solvent/water mixed systems

被引:14
作者
Lee, Seungjun [1 ]
Potts, Jeffrey R. [2 ,3 ]
Oh, Junghoon [1 ]
Han, Jongwoo [1 ]
Park, Gyutae [1 ]
Park, Sungjin [1 ]
机构
[1] Inha Univ, Dept Chem, 100 Inha Ro, Inchon 402751, South Korea
[2] Univ Texas Austin, Dept Mech Engn, Austin, TX 78712 USA
[3] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA
关键词
N-Doping; Reduced graphene oxide; Colloidal suspensions; Ammonia; Paper materials; NITROGEN-DOPED GRAPHENE; EXFOLIATED GRAPHITE OXIDE; FUNCTIONALIZED GRAPHENE; AQUEOUS DISPERSIONS; FACILE SYNTHESIS; REDUCTION; SHEETS; NANOSHEETS; FILMS; PAPER;
D O I
10.1016/j.solidstatesciences.2013.10.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The production of colloidal suspensions of graphene-based nano-platelets in large scale is highly important for their use in practical applications. In this work, we developed a new route for generation of colloidal suspensions of N-modified graphene-based nano-platelets (A-rG-O) with high concentration in water or organic solvent/water mixed systems by the reaction between graphene oxide and ammonium hydroxide. Graphene oxide was reduced by the ammonium hydroxide and N atoms (up to 6 at%) were introduced into A-rG-O materials using solution process without further thermal treatment. Such A-rG-O nano-platelets were well dispersed as individual layers in both systems. Macroscopic free-standing A-rG-O paper materials with good electrical conductivity were produced by filtration of such colloidal suspensions. (C) 2013 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
相关论文
共 47 条
[1]   Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics [J].
Berger, C ;
Song, ZM ;
Li, TB ;
Li, XB ;
Ogbazghi, AY ;
Feng, R ;
Dai, ZT ;
Marchenkov, AN ;
Conrad, EH ;
First, PN ;
de Heer, WA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) :19912-19916
[2]  
Brodie B., 1860, ANN CHIM PHYS, V59, P466
[3]   Mechanically strong, electrically conductive, and biocompatible graphene paper [J].
Chen, Haiqun ;
Mueller, Marc B. ;
Gilmore, Kerry J. ;
Wallace, Gordon G. ;
Li, Dan .
ADVANCED MATERIALS, 2008, 20 (18) :3557-+
[4]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[5]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[6]   Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation [J].
Fan, Xiaobin ;
Peng, Wenchao ;
Li, Yang ;
Li, Xianyu ;
Wang, Shulan ;
Zhang, Guoliang ;
Zhang, Fengbao .
ADVANCED MATERIALS, 2008, 20 (23) :4490-4493
[7]   Radio-frequency plasma functionalization of carbon nanotubes surface O2, NH3, and CF4 treatments -: art. no. 074308 [J].
Felten, A ;
Bittencourt, C ;
Pireaux, JJ ;
Van Lier, G ;
Charlier, JC .
JOURNAL OF APPLIED PHYSICS, 2005, 98 (07)
[8]   Three-Dimensional Pt-on-Pd Bimetallic Nanodendrites Supported on Graphene Nanosheet: Facile Synthesis and Used as an Advanced Nanoelectrocatalyst for Methanol Oxidation [J].
Guo, Shaojun ;
Dong, Shaojun ;
Wang, Erkang .
ACS NANO, 2010, 4 (01) :547-555
[9]   Generation of B-Doped Graphene Nanoplatelets Using a Solution Process and Their Supercapacitor Applications [J].
Han, Jongwoo ;
Zhang, Li Li ;
Lee, Seungjun ;
Oh, Junghoon ;
Lee, Kyoung-Seok ;
Potts, Jeffrey R. ;
Ji, Junyi ;
Zhao, Xin ;
Ruoff, Rodney S. ;
Park, Sungjin .
ACS NANO, 2013, 7 (01) :19-26
[10]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339