Three-dimensional iron(II) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

被引：31

作者：

Shin, Jong Won ^{[1
]}

Jeong, Ah Rim ^{[1
]}

Jeoung, Sungeun ^{[2
]}

Moon, Hoi Ri ^{[2
]}

Komatsumaru, Yuki ^{[3
]}

Hayami, Shinya ^{[3
]}

Moon, Dohyun ^{[4
]}

Min, Kil Sik ^{[5
]}

机构：

[1] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea

[2] Ulsan Natl Inst Sci & Technol, Dept Chem, Ulsan 44919, South Korea

[3] Kumamoto Univ, Dept Chem, Kumamoto 8608555, Japan

[4] Pohang Accelerator Lab POSTECH, Beamline Dept, Pohang 37673, South Korea

[5] Kyungpook Natl Univ, Dept Chem Educ, Daegu 41566, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 34期

基金：

新加坡国家研究基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; SINGLE-MOLECULE-MAGNET; CO2; SORPTION; ADSORPTION; TRANSITION; MECHANISM; BEHAVIOR; CRYSTAL; CAPTURE; NETWORK;

D O I：

10.1039/c8cc00678d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a three-dimensional Fe(II) porous coordination polymer that exhibits a spin crossover temperature change following CO2 sorption (though not N-2 sorption). Furthermore, single crystals of the desolvated polymer with CO2 molecules at three different temperatures were characterised by X-ray crystallography.

引用

页码：4262 / 4265

页数：4

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