FeCl3-Catalyzed 1,2-Addition Reactions of Aryl Aldehydes with Arylboronic Acids

被引：69

作者：

Zou, Tao ^{[1
]}

Pi, Sha-Sha ^{[1
]}

Li, Jin-Heng ^{[1
,2
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Sci, Wenzhou 325035, Peoples R China

[2] Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Hunan, Peoples R China

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 02期

基金：

中国国家自然科学基金;

关键词：

RHODIUM-CATALYZED ADDITION; ONE-POT SYNTHESIS; AROMATIC-ALDEHYDES; ORGANOBORONIC ACIDS; ASYMMETRIC 1,4-ADDITION; CARBENE LIGANDS; BORONIC ACIDS; ARYLATION; KETONES; COMPLEXES;

D O I：

10.1021/ol802529p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel protocol for the 1,2-addition reactions of electron-deficient aryl aldehydes with arylboronic acids using an inexpensive and environmentally benign iron catalyst is reported. In the presence of FeCl3 and 2-(di-tert-butylphosphino)biphenyl, 1,2-addition reactions of various electron-deficient aryl aldehydes with arylboronic acids provided the corresponding biaryl methanols in moderate to excellent yields.

引用

页码：453 / 456

页数：4

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