Ultrahigh humidity sensitivity of graphene oxide

被引:507
作者
Bi, Hengchang [1 ]
Yin, Kuibo [1 ]
Xie, Xiao [1 ]
Ji, Jing [1 ]
Wan, Shu [1 ]
Sun, Litao [1 ]
Terrones, Mauricio [2 ,3 ]
Dresselhaus, Mildred S. [4 ,5 ]
机构
[1] Southeast Univ, Minist Educ, Key Lab MEMS, SEU FEI Nano Pico Ctr, Nanjing 210096, Jiangsu, Peoples R China
[2] Penn State Univ, Dept Phys, Dept Mat Sci & Engn, Ctr Dimens & Layered Mat 2, University Pk, PA 16802 USA
[3] Shishu Univ, Res Ctr Exot Nanocarbons, Nagano 3808553, Japan
[4] MIT, Dept Phys, Cambridge, MA 02139 USA
[5] MIT, Dept Elect Engn & Comp Sci, Cambridge, MA 02139 USA
基金
中国国家自然科学基金;
关键词
CARBON NANOTUBES; FILMS; TRANSPARENT; ADSORPTION; COMPOSITE; MOLECULES; SENSORS; SILICON; NO2;
D O I
10.1038/srep02714
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Humidity sensors have been extensively used in various fields, and numerous problems are encountered when using humidity sensors, including low sensitivity, long response and recovery times, and narrow humidity detection ranges. Using graphene oxide (G-O) films as humidity sensing materials, we fabricate here a microscale capacitive humidity sensor. Compared with conventional capacitive humidity sensors, the G-O based humidity sensor has a sensitivity of up to 37800% which is more than 10 times higher than that of the best one among conventional sensors at 15%-95% relative humidity. Moreover, our humidity sensor shows a fast response time (less than 1/4 of that of the conventional one) and recovery time (less than 1/2 of that of the conventional one). Therefore, G-O appears to be an ideal material for constructing humidity sensors with ultrahigh sensitivity for widespread applications.
引用
收藏
页数:7
相关论文
共 54 条
[1]   THE GROTTHUSS MECHANISM [J].
AGMON, N .
CHEMICAL PHYSICS LETTERS, 1995, 244 (5-6) :456-462
[2]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[3]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[4]   Synthesis and solid-state NMR structural characterization of 13C-labeled graphite oxide [J].
Cai, Weiwei ;
Piner, Richard D. ;
Stadermann, Frank J. ;
Park, Sungjin ;
Shaibat, Medhat A. ;
Ishii, Yoshitaka ;
Yang, Dongxing ;
Velamakanni, Aruna ;
An, Sung Jin ;
Stoller, Meryl ;
An, Jinho ;
Chen, Dongmin ;
Ruoff, Rodney S. .
SCIENCE, 2008, 321 (5897) :1815-1817
[5]   Adsorption of NH3 and NO2 molecules on carbon nanotubes [J].
Chang, H ;
Lee, JD ;
Lee, SM ;
Lee, YH .
APPLIED PHYSICS LETTERS, 2001, 79 (23) :3863-3865
[6]   A Capacitive Humidity Sensor Based on Multi-Wall Carbon Nanotubes (MWCNTs) [J].
Chen, Wei-Ping ;
Zhao, Zhen-Gang ;
Liu, Xiao-Wei ;
Zhang, Zhong-Xin ;
Suo, Chun-Guang .
SENSORS, 2009, 9 (09) :7431-7444
[7]   Humidity sensing behavior of silicon nanowires with hexamethyldisilazane modification [J].
Chen, Xuejiao ;
Zhang, Jian ;
Wang, Zhiliang ;
Yan, Qiang ;
Hui, Shichao .
SENSORS AND ACTUATORS B-CHEMICAL, 2011, 156 (02) :631-636
[8]   Highly sensitive humidity sensor based on amorphous Al2O3 nanotubes [J].
Cheng, Baochang ;
Tian, Baixiang ;
Xie, Cuicui ;
Xiao, Yanhe ;
Lei, Shuijin .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (06) :1907-1912
[9]   Suspended Graphene Sensors with Improved Signal and Reduced Noise [J].
Cheng, Zengguang ;
Li, Qiang ;
Li, Zhongjun ;
Zhou, Qiaoyu ;
Fang, Ying .
NANO LETTERS, 2010, 10 (05) :1864-1868
[10]  
Cho ES, 2012, NAT MATER, V11, P978, DOI [10.1038/NMAT3406, 10.1038/nmat3406]