A Photo Touch on Amines: New Synthetic Adventures of Nitrogen Radical Cations

被引：109
作者：
Maity, Soumitra [1 ]
Zheng, Nan [1 ]
机构：
[1] Univ Arkansas, Dept Chem & Biochem, Fayetteville, AR 72701 USA
来源：
SYNLETT | 2012年 / 13期
关键词：
amines; visible light; nitrogen radical cations; ruthenium; iridium; VISIBLE-LIGHT PHOTOCATALYSIS; C-H ARYLATION; AEROBIC OXIDATION; TERTIARY AMINOCYCLOPROPANES; CATALYSIS; COMPLEXES; CYCLOPROPYLAMINES; PHOTOCHEMISTRY; CYCLOADDITIONS; HETEROARENES;
D O I：
10.1055/s-0032-1316592
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Amines have been used as sacrificial electron donors to reduce photoexcited Ru(II) or Ir(III) complexes, during which they are oxidized to nitrogen radical cations. Recently, the synthetic potential of these nitrogen radical cations have caught synthetic organic chemists' attention. They have been exploited in various transformations yielding a number of elegant methods for amine synthesis. This article highlights recent developments on nitrogen radical cation chemistry under visible-light photocatalysis.
引用
收藏
页码：1851 / 1856
页数：6
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