Rational design of high quality citric acid-derived carbon dots by selecting efficient chemical structure motifs

A green pyrolysis approach to prepare ultra-small nitrogen and sulfur-co-doped carbon dots (N,S-C-dots, QY reaches 55.7%) with precursors citric acid (CA) as carbon source and N-acetyl-L-cysteine as N and S dopant has been explored. The optical properties and the origin of photoluminescence (PL) have been investigated at length. The mixed excitation independence character (200 < lambda(ex) < 380 nm) and the excitation dependence feature (lambda(ex) > 380 nm) along with the biexponential behavior of lifetime of prepared C-dots all indicate the existence of two different emissive sites: the surface state caused by the introducing of N and Son C-dots surfaces and the molecular state induced by the fluorophores covalently bonded onto C-dots surfaces. More importantly, for the first time, through comprehensively comparing the PL performances of various types of N,S-C-dots, N-C-dots and S-C-dots synthesized under same condition, we report the efficient chemical structure motif of reactant, which could form small fluorophore molecules with high PL during the synthesis and thus exhibits favorable impact on PL performances of resulting C-dots. Detailed structural and property studies suggest that the chemical structure motif of reactant (-HN-C-C-SH) determines the optical properties of CA-derived C-dots, which would be valuable in selecting efficient reactants for preparing highly fluorescent CA-derived C-dots. (C) 2016 Elsevier Ltd. All rights reserved.