Role of solvents on the electrical conductivity of solution-processed poly (methyl methacrylate) thin films

被引:2
作者
Biswas, Bipul [1 ]
Chowdhury, Avijit [1 ]
Mallik, Biswanath [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Spect, Kolkata 700032, India
关键词
Polymer; Thin film; Current-voltage characteristics; Hysteresis; Effects of solvents; TEMPERATURE; PROPERTY; HUMIDITY; CAST; PMMA;
D O I
10.1016/j.synthmet.2013.06.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The role of solvents on the current-voltage characteristics of solution-processed poly(methyl methacrylate) (PMMA) thin films prepared by drop casting method, using solvents of different boiling points, has been studied under different experimental conditions. Hysteresis in current-voltage characteristics, area within the hysteresis loops, short-circuit current, open-circuit voltage and surface morphology of the PMMA films have been observed to depend on the boiling point of the solvents from which the films were prepared. Dependence of various parameters on the solvent boiling points in the present experiment is related to the amount of solvent vapour absorbed (or adsorbed) in the PMMA films. The results have been explained on the basis of molecular reorganization in PMMA and creation of different conduction paths during forward and reverse bias. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:44 / 51
页数:8
相关论文
共 32 条
  • [1] Detailed studies on the photoswitching property of ferrocene-doped poly(methyl methacrylate) thin films containing chloroform molecules
    Basak, D
    Mallik, B
    [J]. SYNTHETIC METALS, 2006, 156 (2-4) : 176 - 184
  • [2] Size selective photoluminescence in poly(methyl methacrylate) thin solid films with dispersed silver nanoparticles synthesized by a novel method
    Basak, D
    Karan, S
    Mallik, B
    [J]. CHEMICAL PHYSICS LETTERS, 2006, 420 (1-3) : 115 - 119
  • [3] Unusual photoinduced changes in the electrical conductivity of ferrocene-doped poly(methyl methacrylate) thin films prepared under different relative humidity condition
    Basak, D
    Mallik, B
    [J]. SYNTHETIC METALS, 2004, 146 (02) : 151 - 158
  • [4] Significant modifications in the electrical properties of poly(methyl methacrylate) thin films upon dispersion of silver nanoparticles
    Basak, Dhrubajyoti
    Karan, Santanu
    Mallik, Biswanath
    [J]. SOLID STATE COMMUNICATIONS, 2007, 141 (09) : 483 - 487
  • [5] Solvent retention in solution-cast films of PMMA: study by dielectric spectroscopy
    Bistac, S
    Schultz, J
    [J]. PROGRESS IN ORGANIC COATINGS, 1997, 31 (04) : 347 - 350
  • [6] Influence of polymer/solvent acid-base interactions on the aggregation of stereoregular PMMA
    Bistac, S
    Schultz, J
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 1997, 198 (02) : 531 - 535
  • [7] Surface electrical conductivity of poly(methyl methacrylate) thin films: Observation of conductivity switching
    Biswas, Bipul
    Chakraborty, Aloke Kumar
    Majumder, Manisree
    Chowdhury, Avijit
    Sanyal, Manik Kr
    Mallik, Biswanath
    [J]. SYNTHETIC METALS, 2012, 161 (23-24) : 2632 - 2637
  • [8] Enhanced mobility of poly(3-hexylthiophene) transistors by spin-coating from high-boiling-point solvents
    Chang, JF
    Sun, BQ
    Breiby, DW
    Nielsen, MM
    Sölling, TI
    Giles, M
    McCulloch, I
    Sirringhaus, H
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (23) : 4772 - 4776
  • [9] Enhanced efficiency of plastic photovoltaic devices by blending with ionic solid electrolytes
    Chen, FC
    Xu, QF
    Yang, Y
    [J]. APPLIED PHYSICS LETTERS, 2004, 84 (16) : 3181 - 3183
  • [10] Polymer solar cells with enhanced open-circuit voltage and efficiency
    Chen, Hsiang-Yu
    Hou, Jianhui
    Zhang, Shaoqing
    Liang, Yongye
    Yang, Guanwen
    Yang, Yang
    Yu, Luping
    Wu, Yue
    Li, Gang
    [J]. NATURE PHOTONICS, 2009, 3 (11) : 649 - 653