Class of Solid-like Electrolytes for Rechargeable Batteries Based on Metal-Organic Frameworks Infiltrated with Liquid Electrolytes

被引：37

作者：

Ma, Shengxiang ^{[1
]}

Shen, Li ^{[1
]}

Liu, Qian ^{[2
]}

Shi, Wenyue ^{[1
]}

Zhang, Chen ^{[1
]}

Liu, Fang ^{[1
]}

Baucom, Jesse A. ^{[1
]}

Zhang, Dong ^{[3
]}

Yue, Huijuan ^{[4
]}

Wu, Hao Bin ^{[2
]}

Lu, Yunfeng ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA

[2] Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China

[3] Jilin Univ, Coll Phys, Key Lab Phys & Technol Adv Batteries Minist Educ, Changchun 130012, Peoples R China

[4] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2020年 / 12卷 / 39期

关键词：

solid-like electrolytes; metal-organic frameworks; open-metal sites; electrolytes beyond Li+; rechargeable batteries; PROPYLENE CARBONATE; ION; LITHIUM; NA; CONDUCTIVITY; SOLVATION; VISCOSITY; MEMBRANE; BEHAVIOR; ISSUES;

D O I：

10.1021/acsami.0c13437

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A new family of solid-like electrolytes was developed by infiltrating MIL-100(Al), an electrochemically stable metal-organic-framework (MOF) material, with liquid electrolytes that contain cations from the 3rd period (Na+, Mg2+, and Al3+) and the 1st group (Li+, Na+, K+, and Cs+). The anions were immobilized within the MOF scaffolds upon complexing with the open metal sites, allowing effective transport of the cations in the nanoporous channels with high conductivity (up to 1 mS cm-1) and low activation energy (down to 0.2 eV). This general approach enables the fabrication of superior conductive solid-like electrolytes beyond lithium ions.

引用

页码：43824 / 43832

页数：9

共 50 条

[1] THE USE OF IONIZATION POTENTIALS .1. IONIC RADII OF THE ELEMENTS [J].

AHRENS, LH .

GEOCHIMICA ET COSMOCHIMICA ACTA, 1952, 2 (03) :155-169

[2] Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert-Butoxide [J].

Ameloot, Rob ;

Aubrey, Michael ;

Wiers, Brian M. ;

Gomora-Figueroa, Ana P. ;

Patel, Shrayesh N. ;

Balsara, Nitash P. ;

Long, Jeffrey R. .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (18) :5533-5536

[3] Metal-organic frameworks as solid magnesium electrolytes [J].

Aubrey, M. L. ;

Ameloot, R. ;

Wiers, B. M. ;

Long, J. R. .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (02) :667-671

[4] Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction [J].

Bachman, John Christopher ;

Muy, Sokseiha ;

Grimaud, Alexis ;

Chang, Hao-Hsun ;

Pour, Nir ;

Lux, Simon F. ;

Paschos, Odysseas ;

Maglia, Filippo ;

Lupart, Saskia ;

Lamp, Peter ;

Giordano, Livia ;

Shao-Horn, Yang .

CHEMICAL REVIEWS, 2016, 116 (01) :140-162

[5] Infrared (attenuated total reflection) study of propylene carbonate solutions containing lithium and sodium perchlorate [J].

Brooksby, Paula A. ;

Fawcett, W. Ronald .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2006, 64 (02) :372-382

[6]

Bulavin LA, 2011, UKR J PHYS, V56, P893

[7] Optimal sizing and location based on economic parameters for an off-grid application of a hybrid system with photovoltaic, battery and diesel technology [J].

Cai, Wei ;

Li, Xing ;

Maleki, Akbar ;

Pourfayaz, Fathollah ;

Rosen, Marc A. ;

Nazari, Mohammad Alhuyi ;

Dieu Tien Bui .

ENERGY, 2020, 201

[8] ATR-FTIR spectroscopic studies on aqueous LiClO4, NaClO4, and Mg(ClO4)2 solutions [J].

Chen, Y ;

Zhang, YH ;

Zhao, LJ .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (03) :537-542

[9] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[10] Conductivity, viscosity and IR spectra of Li, Na and Mg perchlorate solutions in propylene carbonate/water mixed solvents [J].

Cvjeticanin, ND ;

Mentus, S .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (22) :5157-5161

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