Synthesis and Catalytic Behavior of Ferrierite Zeolite Nanoneedles

被引：61

作者：

Lee, Yoorim ^{[1
,2
]}

Park, Min Bum ^{[1
,2
]}

Kim, Pyung Soon ^{[1
,2
]}

Vicente, Aurelie ^{[3
]}

Fernandez, Christian ^{[3
]}

Nam, In-Sik ^{[1
,2
]}

Hong, Suk Bong ^{[1
,2
]}

机构：

[1] POSTECH, Dept Chem Engn, Pohang 790784, South Korea

[2] POSTECH, Sch Environm Sci & Engn, Pohang 790784, South Korea

[3] Univ Caen, ENSICAEN, Lab Catalyse & Spectrochim, CNRS, F-14050 Caen, France

来源：

ACS CATALYSIS | 2013年 / 3卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

ferrierite zeolite nanoneedles; synthesis; characterization; catalytic properties; SKELETAL ISOMERIZATION; COKE DEPOSITS; N-BUTENES; 1-BUTENE; SILICATE; ORIGIN;

D O I：

10.1021/cs400025s

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The proton form of nanosized, needlelike ferrierite zeolite, which was synthesized using choline and Na+ cations as structure-directing agents, was found to be much more efficient for the skeletal isomerization of 1-butene to isobutene than the corresponding cation form of conventional, submicrometric ferrierite with a platelike shape, mainly because of the considerably lower density of strong acid sites, but as well as a result of the higher density of 10-ring pore mouths.

引用

页码：617 / 621

页数：5

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