A high performance nitrogen-doped porous activated carbon for supercapacitor derived from pueraria

被引:100
作者
Han, Xiuli [1 ]
Jiang, Haixia [1 ]
Zhou, Yong [1 ]
Hong, Weifeng [1 ]
Zhou, Yangfan [1 ]
Gao, Ping [1 ]
Ding, Rui [1 ]
Liu, Enhui [1 ]
机构
[1] Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Pueraria; Biomass carbon; Porous; Nitrogen-doped; Supercapacitor; DOUBLE-LAYER CAPACITANCE; ELECTROCHEMICAL CAPACITORS; ELECTRODE MATERIAL; MELAMINE; PYROLYSIS; BATTERIES; BIOMASS;
D O I
10.1016/j.jallcom.2018.02.078
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, pueraria-based biomass nitrogen-doped porous activated carbon (NPC) was prepared by a simple two-step approach. Firstly, pueraria powder and melamine were fully mixed and hydrothermally treated. Secondly, the as-formed product was directly subjected to the oven for the simultaneous pyrolysis and activation. The as-prepared samples were systematically characterized by SEM, TEM, XPS, XRD, and N-2 sorption isotherms techniques. The as-prepared NPC exhibited a high BET surface area of 2321 m(2) g(-1) with 99% small-size mesoporous structures. In 6 M KOH electrolyte, the NPC electrode delivered a high specific capacitance of 250 F g(-1) at a current density of 0.5 A g(-1). Even at 10 A g(-1), specific capacitance of 231 F g(-1) was obtained. Furthermore, an energy density of 8.46 Wh kg(-1) at a power density of 123 W kg(-1) was obtained with the NPC electrode in a supercapacitor, and it still retained a specific energy density of 7.52 Wh kg(-1) at a power density of 2417 W kg(-1). (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:544 / 551
页数:8
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