A high performance nitrogen-doped porous activated carbon for supercapacitor derived from pueraria

被引:100
作者
Han, Xiuli [1 ]
Jiang, Haixia [1 ]
Zhou, Yong [1 ]
Hong, Weifeng [1 ]
Zhou, Yangfan [1 ]
Gao, Ping [1 ]
Ding, Rui [1 ]
Liu, Enhui [1 ]
机构
[1] Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Pueraria; Biomass carbon; Porous; Nitrogen-doped; Supercapacitor; DOUBLE-LAYER CAPACITANCE; ELECTROCHEMICAL CAPACITORS; ELECTRODE MATERIAL; MELAMINE; PYROLYSIS; BATTERIES; BIOMASS;
D O I
10.1016/j.jallcom.2018.02.078
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, pueraria-based biomass nitrogen-doped porous activated carbon (NPC) was prepared by a simple two-step approach. Firstly, pueraria powder and melamine were fully mixed and hydrothermally treated. Secondly, the as-formed product was directly subjected to the oven for the simultaneous pyrolysis and activation. The as-prepared samples were systematically characterized by SEM, TEM, XPS, XRD, and N-2 sorption isotherms techniques. The as-prepared NPC exhibited a high BET surface area of 2321 m(2) g(-1) with 99% small-size mesoporous structures. In 6 M KOH electrolyte, the NPC electrode delivered a high specific capacitance of 250 F g(-1) at a current density of 0.5 A g(-1). Even at 10 A g(-1), specific capacitance of 231 F g(-1) was obtained. Furthermore, an energy density of 8.46 Wh kg(-1) at a power density of 123 W kg(-1) was obtained with the NPC electrode in a supercapacitor, and it still retained a specific energy density of 7.52 Wh kg(-1) at a power density of 2417 W kg(-1). (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:544 / 551
页数:8
相关论文
共 38 条
[1]   Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review [J].
Abioye, Adekunle Moshood ;
Ani, Farid Nasir .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 52 :1282-1293
[2]   Formation and characterization of flower-like carbon nitride by pyrolysis of melamine [J].
Bai, Xinjiao ;
Cao, Chuanbao ;
Xu, Xingyan .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2010, 175 (02) :95-99
[3]   From dead leaves to high energy density supercapacitors [J].
Biswal, Mandakini ;
Banerjee, Abhik ;
Deo, Meenal ;
Ogale, Satishchandra .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) :1249-1259
[4]   TRANSITION FROM SUPERCAPACITOR TO BATTERY BEHAVIOR IN ELECTROCHEMICAL ENERGY-STORAGE [J].
CONWAY, BE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (06) :1539-1548
[5]   Hierarchical porous carbon microspheres derived from porous starch for use in high-rate electrochemical double-layer capacitors [J].
Du, Si-hong ;
Wang, Li-qun ;
Fu, Xiao-ting ;
Chen, Ming-ming ;
Wang, Cheng-yang .
BIORESOURCE TECHNOLOGY, 2013, 139 :406-409
[6]   Hierarchical Nanostructured Carbons with Meso-Macroporosity: Design, Characterization, and Applications [J].
Fang, Baizeng ;
Kim, Jung Ho ;
Kim, Min-Sik ;
Yu, Jong-Sung .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (07) :1397-1406
[7]  
Gregg S.J., 1967, J ELECTROCHEM SOC, V114, P279, DOI [DOI 10.1016/0021-9797(83)90305-3, DOI 10.1149/1.2426447]
[8]   Effect of pore size distribution of coal-based activated carbons on double layer capacitance [J].
Gryglewicz, G ;
Machnikowski, J ;
Lorenc-Grabowska, E ;
Lota, G ;
Frackowiak, E .
ELECTROCHIMICA ACTA, 2005, 50 (05) :1197-1206
[9]   Influence of oxygen treatment on electric double-layer capacitance of activated carbon fabrics [J].
Hsieh, CT ;
Teng, H .
CARBON, 2002, 40 (05) :667-674
[10]   Hierarchical Porous Graphene Carbon-Based Supercapacitors [J].
Huang, Jianlin ;
Wang, Junyin ;
Wang, Congwei ;
Zhang, Huinian ;
Lu, Chunxiang ;
Wang, Junzhong .
CHEMISTRY OF MATERIALS, 2015, 27 (06) :2107-2113