Theoretical Studies on 2-Hexylthieno[3,2-b]thiophene End-Capped Oligomers for Organic Semiconductor Materials

被引：0
|
作者：
Park, Young Hee [1 ,2 ]
Kim, Yun-Hi [2 ,3 ]
Kwon, Soon-Ki [4 ,5 ]
Koo, In Sun [1 ,2 ]
Yang, Kiyull [1 ,2 ]
机构：
[1] Gyeongsang Natl Univ, Dept Chem Educ, Jinju 660701, South Korea
[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea
[3] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea
[4] Gyeongsang Natl Univ, Sch Mat Sci & Engn, Jinju 660701, South Korea
[5] Gyeongsang Natl Univ, ERI, Jinju 660701, South Korea
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2012年 / 33卷 / 04期
关键词：
Reorganization energy; Organic thin film transistor; Hole transport; Organic semiconductor; Density functional theory; FIELD-EFFECT TRANSISTORS; THIN-FILM-TRANSISTOR; DENSITY-FUNCTIONAL THEORY; HIGH-PERFORMANCE; ENERGY-TRANSFER; CONJUGATED OLIGOMERS; ELECTRONIC-STRUCTURE; P-TYPE; CHARGE; POLYMERS;
D O I：
10.5012/bkcs.2012.33.4.1213
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reorganization energy and the spectroscopic properties of 2,6-bis(5'-hexyl-thieno[3,2-b]thiophene-2'-yl)naphthalene (DH-TNT) and 2,6-bis(5'-hexyl-thieno[3,2-b]thiophene-2'-yl)anthracene (DH-TAT), which are composed of an acene unit and alkylated thienothiophene on both sides, as organic materials for display devices were calculated and the results were compared with experimental values. The lower reorganization energy of the DH-TAT over the DH-TNT calculated by the density functional theory is attributed to a smaller vibrational distortion because of the heavier building block of DH-TAT, and it shows a good field effect performance over the DH-TNT. The calculated spectra and the other spectroscopic characteristic of the compounds are well consistent with those of observed results.
引用
收藏
页码：1213 / 1219
页数：7
相关论文
共 50 条
  • [21] METALLATION OF THIENO(2,3-B)THIOPHENE OR THIENO(3,2-B) THIOPHENE WITH BUTYLLITHIUM
    BUGGE, A
    SVENSK KEMISK TIDSKRIFT, 1967, 79 (10): : 563 - &
  • [22] METALATION OF THIENO[2,3-B]THIOPHENE AND THIEN/(3,2-B]THIOPHENE WITH BUTYLLITHIUM
    BUGGE, A
    ACTA CHEMICA SCANDINAVICA, 1968, 22 (01): : 63 - &
  • [23] Synthesis, crystal structure, and polymerization of butterfly-shaped thieno[3,2-b]thiophene oligomers
    Liu, Ying
    Liu, Qida
    Zhang, Xingye
    Ai, Ling
    Wang, Yang
    Peng, Ruixiang
    Ge, Ziyi
    NEW JOURNAL OF CHEMISTRY, 2013, 37 (04) : 1189 - 1194
  • [24] Amorphous Thieno[3,2-b]thiophene and Benzothiadiazole Based Copolymers for Organic Photovoltaics
    Lee, Wonho
    Cha, Hyojun
    Kim, Yu Jin
    Jeong, Ji-Eun
    Hwang, Sungu
    Park, Chan Eon
    Woo, Han Young
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (22) : 20510 - 20518
  • [25] A Novel Series of Thermally and Electrically Stable Hole-transporters End-capped by [1]Benzothieno[3,2-b][1] benzothiophenes for Organic Light-emitting Devices
    Kikuchi, Takayoshi
    Sasabe, Hisahiro
    Watanabe, Yuichiro
    Kamata, Takahiro
    Katagiri, Hiroshi
    Kido, Junji
    CHEMISTRY LETTERS, 2019, 48 (03) : 219 - 222
  • [26] Thieno[3,2-b]thiophene oligomers and their applications as p-type organic semiconductors (vol 19, pg 3449, 2009)
    Ahmed, Moawia O.
    Wang, Chunmei
    Keg, Peisi
    Pisula, Wojciech
    Lam, Yeng-Ming
    Ong, Beng S.
    Ng, Siu-Choon
    Chen, Zhi-Kuan
    Mhaisalkar, Subodh G.
    JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (48) : 9288 - 9288
  • [27] Bulky End-Capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching High-Mobility Organic Semiconductors by Fine Tuning of the Crystalline Solid-State Order
    Schweicher, Guillaume
    Lemaur, Vincent
    Niebel, Claude
    Ruzie, Christian
    Diao, Ying
    Goto, Osamu
    Lee, Wen-Ya
    Kim, Yeongin
    Arlin, Jean-Baptiste
    Karpinska, Jolanta
    Kennedy, Alan R.
    Parkin, Sean R.
    Olivier, Yoann
    Mannsfeld, Stefan C. B.
    Cornil, Jerome
    Geerts, Yves H.
    Bao, Zhenan
    ADVANCED MATERIALS, 2015, 27 (19) : 3066 - 3072
  • [28] Dialkyl-substituted thieno[3,2-b]thiophene-based polymers containing 2,2'-bithiophene, thieno[3,2-b]thiophene, and ethynylene spacers
    Miguel, Lidaris San
    Matzger, Adam J.
    MACROMOLECULES, 2007, 40 (26) : 9233 - 9237
  • [29] Decyl-end-capped thiophene-phenylene oligomers as organic semiconducting materials with improved oxidation stability
    Ponomarenko, SA
    Kirchmeyer, S
    Elschner, A
    Alpatova, NM
    Halik, M
    Klauk, H
    Zschieschang, U
    Schmid, G
    CHEMISTRY OF MATERIALS, 2006, 18 (02) : 579 - 586
  • [30] 2,5-Bis(trimethylsilylethynyl)thieno[3,2-b]thiophene
    Khan, MS
    Al-Naamani, RS
    Ahrens, B
    Raithby, PR
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O1202 - O1203
12345