Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework

被引：67

作者：

Sapianik, Aleksandr A. ^{[1
,2
]}

Kovalenko, Konstantin A. ^{[1
,2
]}

Samsonenko, Denis G. ^{[1
,2
]}

Barsukova, Marina O. ^{[1
,2
]}

Dybtsev, Danil N. ^{[1
,2
]}

Fedin, Vladimir P. ^{[1
,2
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Akad Lavrentiev Av, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, 2 Pirogova St, Novosibirsk 630090, Russia

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 59期

基金：

俄罗斯科学基金会;

关键词：

COORDINATION POLYMERS; SELECTIVE SORPTION; GAS SORPTION; ADSORPTION; BENZENE; CYCLOHEXANE; FLEXIBILITY; CHANNEL; STORAGE; MOF;

D O I：

10.1039/d0cc03227a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using a series of isoreticular MOFs with void connections of varying diameters, the selective separation of benzene and cyclohexane in both liquid and vapor phases is shown. The driving force of the highly efficient adsorption process is the formation of weak interactions between the adsorbed benzene molecules and the host framework.

引用

页码：8241 / 8244

页数：4

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