A SIMPLE STOCHASTIC KINETIC TRANSPORT MODEL

被引:0
作者
Dekking, Michel [1 ]
Kong, Derong [1 ]
机构
[1] Delft Univ Technol, Appl Math Inst 3TU, Fac EWI, NL-2600 GA Delft, Netherlands
基金
中国国家自然科学基金;
关键词
Markov binomial distribution; reactive transport; kinetic adsorption; solute transport; multimodality; double peak;
D O I
10.1239/aap/1346955268
中图分类号
O21 [概率论与数理统计]; C8 [统计学];
学科分类号
020208 ; 070103 ; 0714 ;
摘要
We introduce a discrete-time microscopic single-particle model for kinetic transport. The kinetics are modeled by a two-state Markov chain, and the transport is modeled by deterministic advection plus a random space step. The position of the particle after n time steps is given by a random sum of space steps, where the size of the sum is given by a Markov binomial distribution (MBD). We prove that by letting the length of the time steps and the intensity of the switching between states tend to 0 linearly, we obtain a random variable S(t), which is closely connected to a well-known (deterministic) partial differential equation (PDE), reactive transport model from the civil engineering literature. Our model explains (via bimodality of the MBD) the double peaking behavior of the concentration of the free part of solutes in the PDE model. Moreover, we show for instantaneous injection of the solute that the partial densities of the free and adsorbed parts of the solute at time t do exist, and satisfy the PDEs.
引用
收藏
页码:874 / 885
页数:12
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