Concomitant Organic-Inorganic UV-Curing Catalyzed by Photoacids

被引：82

作者：

Chemtob, Abraham ^{[1
]}

Versace, Davy-Louis ^{[1
]}

Belon, Cindy ^{[1
]}

Croutxe-Barghorn, Cine ^{[1
]}

Rigolet, Severinne ^{[2
]}

机构：

[1] Univ Haute Alsace, CNRS UMR 7525, Dept Photochem, ENSCMu, F-68093 Mulhouse, France

[2] Univ Haute Alsace, CNRS UMR 7016, Lab Mat Porosite Controlee, ENSCMu, F-68093 Mulhouse, France

来源：

MACROMOLECULES | 2008年 / 41卷 / 20期

关键词：

D O I：

10.1021/ma801017k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Organic-inorganic UV-curing of organosilanes containing epoxy and trialkoxysilyl functional groups in the same monomer was implemented using a diaryl iodonium salt as cationic photoinitiator. UV-generated Bronsted acids through photolytic degradation Were found to be effective in catalyzing both epoxy ring-opening polymerization and alkoxysilane sol-gel polycondensation reactions. Competition between the formation of inorganic and organic phases was kinetically studied using real-time Fourier transform infrared spectroscopy (RT-FTIR). The nature of the hybrid monomer. the effect of changing the film thickness, the type of substrate and the influence of laminated conditions oil the polymerization kinetics were assessed. Si-29 and C-13 solid state NMR measurements were also performed to investigate the structure of the UV-cured hybrid materials.

引用

页码：7390 / 7398

页数：9

共 57 条

[1]

Ajayan M. P., 2003, NANOCOMPOSITE SCI TE

[2] Inorganic-organic polymers as migration barriers against liquid and volatile compounds [J].

Amberg-Schwab, S ;

Katschorek, H ;

Weber, U ;

Burger, A ;

Hänsel, R ;

Steinbrecher, B ;

Harzer, D .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) :699-703

[3] Preparation and characterization of hybrid nanocomposite coatings by photopolymerization and sol-gel process [J].

Amerio, E ;

Sangermano, M ;

Malucelli, G ;

Priola, A ;

Voit, B .

POLYMER, 2005, 46 (25) :11241-11246

[4] Preparation and characterization of hyperbranched polymer/silica hybrid nanocoatings by dual-curing process [J].

Amerio, Ezio ;

Sangermano, Marco ;

Malucelli, Giulio ;

Priola, Aldo ;

Rizza, Giancarlo .

MACROMOLECULAR MATERIALS AND ENGINEERING, 2006, 291 (10) :1287-1292

[5] UV curable acrylate nanocomposites: Properties and applications [J].

Bauer, F ;

Mehnert, R .

JOURNAL OF POLYMER RESEARCH, 2005, 12 (06) :483-491

[6] Photocurable glycidoxypropyltrimethoxysilane based sol-gel hybrid materials [J].

Brusatin, Giovanna ;

Della Giustina, Giola ;

Guglielmi, Massimo ;

Innocenzi, Plinio .

PROGRESS IN SOLID STATE CHEMISTRY, 2006, 34 (2-4) :223-229

[7] Photocuring kinetics of UV-initiated free-radical photopolymerizations with and without silica nanoparticles [J].

Cho, JD ;

Ju, HT ;

Hong, JW .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (03) :658-670

[8] Integrated optics based on organo-mineral materials [J].

Coudray, P ;

Etienne, P ;

Moreau, Y .

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2000, 3 (5-6) :331-337

[9] CATIONIC PHOTOPOLYMERIZATION OF AMBIFUNCTIONAL MONOMERS [J].

CRIVELLO, JV ;

BI, DS ;

LU, YJ .

MACROMOLECULAR SYMPOSIA, 1995, 95 :79-89

[10] Preparation and cationic photopolymerization of organic-inorganic hybrid matrixes [J].

Crivello, JV ;

Mao, ZB .

CHEMISTRY OF MATERIALS, 1997, 9 (07) :1562-1569

← 1 2 3 4 5 6 →