N-Iodosuccinimide: A Highly Effective Regioselective Reagent for Iodoesterification of Alkenes

被引：11

作者：

Reddy, Aleti R. ^{[1
]}

Sangwan, Payare L. ^{[1
]}

Chinthakindi, Praveen K. ^{[1
]}

Farooq, Saleem ^{[1
]}

Siddaiah, Vidavalur ^{[2
]}

Koul, Surrinder ^{[1
]}

机构：

[1] CSIR Indian Inst Integrat Med, Bioorgan Chem Div, Jammu 180001, Tawi, India

[2] Andhra Univ, Dept Organ Chem Food Drugs & Water, Visakhapatnam 530003, Andhra Pradesh, India

来源：

HELVETICA CHIMICA ACTA | 2013年 / 96卷 / 07期

关键词：

Alkenes; N-Iodosuccinimide (NIS); Iodohydrins; Iodoesterification; ODORLESS BENZENETHIOLS; BENZENESULFINIC ACID; AMINOHALOGENATION; BROMINATION; IODOHYDRINS; DERIVATIVES; HALOHYDRINS; CONVERSION; OLEFINS; AMINES;

D O I：

10.1002/hlca.201200383

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rapid, convenient, and efficient method has been achieved for regioselective iodoesterification of alkenes with aliphatic and aromatic acids, and protected amino acids in the presence of N-iodosuccinimide (NIS) in nearly quantitative yields. Optically enriched iodohydrins have been achieved by LiAlH4 (LAH) reduction of diastereoisomeric iodo esters.

引用

页码：1313 / 1324

页数：12

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