N-Iodosuccinimide: A Highly Effective Regioselective Reagent for Iodoesterification of Alkenes

被引：11
|
作者：
Reddy, Aleti R. [1 ]
Sangwan, Payare L. [1 ]
Chinthakindi, Praveen K. [1 ]
Farooq, Saleem [1 ]
Siddaiah, Vidavalur [2 ]
Koul, Surrinder [1 ]
机构：
[1] CSIR Indian Inst Integrat Med, Bioorgan Chem Div, Jammu 180001, Tawi, India
[2] Andhra Univ, Dept Organ Chem Food Drugs & Water, Visakhapatnam 530003, Andhra Pradesh, India
来源：
HELVETICA CHIMICA ACTA | 2013年 / 96卷 / 07期
关键词：
Alkenes; N-Iodosuccinimide (NIS); Iodohydrins; Iodoesterification; ODORLESS BENZENETHIOLS; BENZENESULFINIC ACID; AMINOHALOGENATION; BROMINATION; IODOHYDRINS; DERIVATIVES; HALOHYDRINS; CONVERSION; OLEFINS; AMINES;
D O I：
10.1002/hlca.201200383
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A rapid, convenient, and efficient method has been achieved for regioselective iodoesterification of alkenes with aliphatic and aromatic acids, and protected amino acids in the presence of N-iodosuccinimide (NIS) in nearly quantitative yields. Optically enriched iodohydrins have been achieved by LiAlH4 (LAH) reduction of diastereoisomeric iodo esters.
引用
收藏
页码：1313 / 1324
页数：12
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