Recent progress in the use of photoirradiation in living radical polymerization

被引：156

作者：

Yamago, Shigeru ^{[1
,2
]}

Nakamura, Yasuyuki ^{[1
,2
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Japan Sci & Technol Agcy, CREST, Tokyo 1020076, Japan

来源：

POLYMER | 2013年 / 54卷 / 03期

关键词：

Living radical polymerization; Photoirradiation; Precision polymer synthesis; ADDITION-FRAGMENTATION CHAIN; N-BUTYL ACRYLATE; TEMPERATURE RAFT POLYMERIZATION; VISIBLE-LIGHT PHOTOCATALYSIS; GAMMA-RAY IRRADIATION; VINYL-ACETATE; METHYL ACRYLATE; AMBIENT-TEMPERATURE; ALTERNATING COPOLYMERIZATION; DEGENERATIVE TRANSFER;

D O I：

10.1016/j.polymer.2012.11.046

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effects of photoirradiation in controlled and living radical polymerization (LRP), namely nitroxide-mediated polymerization (NMP), atom-transfer radical polymerization (ATRP), cobalt-mediated radical polymerization (CMRP), reversible addition-fragmentation chain transfer polymerization (RAFT), organoiodine-mediated radical polymerization (IRP), and organotellurium-mediated radical polymerization (TERP), are summarized. As in the conventional radical polymerization, photoirradiation has been used for generating radicals under mild conditions in LRP methods. In addition to this use, photoirradiation is also used to overcome the difficulties characteristic to each method, such as activation of catalysis, generation of controlling agents, and increasing the polymer-end structure. The most-recent developments in the use of photochemistry in LRP are summarized in this review. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：981 / 994

页数：14

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