Molecular functionalization of tantalum oxide surface towards development of apatite growth

被引：11

作者：

Aubry, D. ^{[1
]}

Volcke, C. ^{[2
]}

Arnould, Ch. ^{[1
]}

Humbert, C. ^{[2
]}

Thiry, P. A. ^{[2
]}

Delhalle, J. ^{[1
]}

Mekhalif, Z. ^{[1
]}

机构：

[1] Univ Namur, FUNDP, Lab Chem & Electrochem Surfaces, B-5000 Namur, Belgium

[2] Univ Namur, FUNDP, Res Ctr Phys Matter & Radiat, B-5000 Namur, Belgium

来源：

APPLIED SURFACE SCIENCE | 2009年 / 255卷 / 09期

关键词：

Biomaterials; Apatite; Tantalum; X-ray photoelectron spectroscopy; Atomic force microscopy; Self-assembled monolayers; SELF-ASSEMBLED MONOLAYERS; ATOMIC-FORCE MICROSCOPY; SIMULATED BODY-FLUID; CALCIUM-PHOSPHATE; NUCLEATION; HYDROXYAPATITE; INTERFACE; MECHANISM;

D O I：

10.1016/j.apsusc.2008.11.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have studied the apatite growth dynamics on tantalum oxide surfaces. This nucleation is obtained via an organosilane intermediate layer between the apatite and the substrate surface. Four organosilane layers (differing by their terminal functionality) were investigated. Their characterization with atomic force microscopy and other techniques such as X-ray photoelectron spectroscopy (XPS) and wetting measurements highlighted the influence of the organosilane terminal groups on the apatite growth rates. Results revealed that apatite is indeed growing faster on phosphate terminal groups than on the three other groups studied (vinyl, hydroxyl and carboxyl). (C) 2008 Elsevier B. V. All rights reserved.

引用

页码：4765 / 4772

页数：8

共 17 条

[1] Resorption kinetics of osseous substitute: Natural coral and synthetic hydroxyapatite [J].

Braye, F ;

Irigaray, JL ;

Jallot, E ;

Oudadesse, H ;

Weber, G ;

Deschamps, N ;

Deschamps, C ;

Frayssinet, P ;

Tourenne, P ;

Tixier, H ;

Terver, S ;

Lefaivre, J ;

Amirabadi, A .

BIOMATERIALS, 1996, 17 (13) :1345-1350

[2] Visualisation of human plasma fibrinogen adsorbed on titanium implant surfaces with different roughness [J].

Cacciafesta, P ;

Hallam, KR ;

Watkinson, AC ;

Allen, GC ;

Miles, MJ ;

Jandt, KD .

SURFACE SCIENCE, 2001, 491 (03) :405-420

[3] Dynamic atomic force microscopy methods [J].

García, R ;

Pérez, R .

SURFACE SCIENCE REPORTS, 2002, 47 (6-8) :197-301

[4] Using self-assembled monolayer technology to probe the mechanical response of the fiber interphase-matrix interphase interface [J].

Holmes, GA ;

Feresenbet, E ;

Raghavan, D .

COMPOSITE INTERFACES, 2003, 10 (06) :515-546

[5] A study on structures and formation mechanisms of self-assembled monolayers of n-alkyltrichlorosilanes using infrared spectroscopy and atomic force microscopy [J].

Iimura, K ;

Nakajima, Y ;

Kato, T .

THIN SOLID FILMS, 2000, 379 (1-2) :230-239

[6] Biological surface science [J].

Kasemo, B .

SURFACE SCIENCE, 2002, 500 (1-3) :656-677

[7] Novel bioactive materials with different mechanical properties [J].

Kokubo, T ;

Kim, HM ;

Kawashita, M .

BIOMATERIALS, 2003, 24 (13) :2161-2175

[8] The role of surface functional groups in calcium phosphate nucleation on titanium foil: a self-assembled monolayer technique [J].

Liu, Q ;

Ding, J ;

Mante, FK ;

Wunder, SL ;

Baran, GR .

BIOMATERIALS, 2002, 23 (15) :3103-3111

[9] Mechanism of apatite formation on wollastonite coatings in simulated body fluids [J].

Liu, XY ;

Ding, CX ;

Chu, PK .

BIOMATERIALS, 2004, 25 (10) :1755-1761

[10] Repassivating tantalum/tantalum oxide surface modification on stainless steel implants [J].

Macionczyk, F ;

Gerold, B ;

Thull, R .

SURFACE & COATINGS TECHNOLOGY, 2001, 142 :1084-1087

← 1 2 →