Inorganic-organic framework complexes based on 5-((4-carboxybenzyl)oxy) isophthalic acid: Photoelectric properties and potential nitrobenzene sensing

被引：13

作者：

Hou, Ya-Nan ^{[1
]}

Song, Jian ^{[1
]}

Bai, Feng-Ying ^{[1
]}

Xing, Yong-Heng ^{[1
]}

机构：

[1] Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2016年 / 440卷

基金：

中国国家自然科学基金;

关键词：

Supramolecular complex; Synthesis; Crystal structure; Luminescent sensing; Photoelectric properties; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SUPRAMOLECULAR ISOMERISM; LIGAND; LUMINESCENCE; FLUORESCENCE; ADSORPTION; SILVER(I); SITES; 2D;

D O I：

10.1016/j.ica.2015.10.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two complexes {[Cd-3(1,10-phen)(3)(HL)(3)]center dot 4.5H(2)O (1) and Co(1,10-phen)(2)(H2L)(2) (2) {H3L = 5-((4-carboxybenzyl) oxy) isophthalic acid, 1,10-phen = phenanthroline)} based on the rigid-flexible mixed tripodal ligand 5-((4-carboxybenzyl) oxy) isophthalic acid were synthesized in the presence of auxiliary ligands under hydrothermal condition. The single crystal X-ray diffraction analysis revealed that complexes 1 and 2 exhibited a one-dimensional framework and a clustered structure, respectively, while both the complexes presented three-dimensional supermolecular network structures at last by the interaction of the hydrogen bonds. Both of complexes 1 and 2 were characterized by elemental analysis, IR spectroscopy, the single crystal X-ray diffraction analysis, and thermogravimetric analysis. In addition, the surface photovoltage spectroscopy (SPS) and electric-field-induced surface photovoltage spectroscopy (EFISPS) showed that complexes 1 and 2 could behave as p-type semiconductors. The photoluminescent (PL) results showed that complex 1 displayed high-sensitivity luminescent sensing function for nitrobenzene. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：69 / 76

页数：8

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