Solvent effects on infrared spectra of 5-methyl-7-methoxy-iso-flavone in single solvent systems

被引：31

作者：

Liu, Q ^{[1
]}

Sang, WQ ^{[1
]}

Xu, XM ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2002年 / 608卷 / 2-3期

关键词：

infrared spectroscopy; solvent effects; spectral correlation; 5-methyl-7-methoxy-iso-flavone; linear solvation energy relationships;

D O I：

10.1016/S0022-2860(01)00965-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared spectroscopy studies of 5-methyl-7-methoxy-iso-flavone in 20 different pure organic solvents were undertaken to investigate the solvent-solute interactions and to correlate solvent properties such as the Kirkwood-Bauer-Magat (KBM) equation, the solvent acceptor number (AN) and the linear solvation energy relationships (LSER), respectively, with the infrared band shift. Little linear relation between dielectric constants and the frequencies showed that the KBM relationship was unsuitable for the complicated molecules. These frequencies exhibited a better correlation with the LSER than the solvent AN. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：253 / 257

页数：5

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