Highly Porous Carbon from Microalga,Chlorella Vulgaris, as an Electrochemical Hydrogen Storage Material

被引:13
作者
Seifi, Hooman [1 ]
Masoum, Saeed [1 ,2 ]
Hosseini Tafreshi, Seyed Ali [2 ]
Seifi, Soodabe [1 ]
Jafari, Seyed Mostafa [1 ]
机构
[1] Univ Kashan, Dept Analyt Chem, Fac Chem, Kashan, Iran
[2] Univ Kashan, Dept Cell & Mol Biol, Fac Chem, Kashan, Iran
关键词
Electrochemical hydrogen storage; Microalga; Chlorella vulgaris; Biomass; Porous carbon; Renewable energy; ACTIVATED CARBON; HIGH-PERFORMANCE; MICROALGAE; CAPACITY; GROWTH; ALGAE; SUPERCAPACITOR; CARBONIZATION; FABRICATION; ELECTRODES;
D O I
10.1149/1945-7111/abaf73
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Chlorella Vulgaris, as a well-known green microalga is considered as a reliable biomass source with vast biotechnological potential to produce various high-performance products. In the present study, porous carbon with a specific surface area was produced via a hydrothermal technique. The investigated materials were characterized by Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), energy-dispersive X-ray (EDX), Brunauer-Emmett-Teller (BET) and transmission electron microscopy (TEM). The electrochemical hydrogen storage (EHS) capacity of the product was investigated by a three-electrode system (chronopotentiometry) in 6 M KOH electrolyte. The microalga-based porous carbons showed a good electrochemical hydrogen storage capacity equal to 1040 mAh g(-1)(3.9 wt%) after 40 cycles. This great capacity principally is due to the porous structure (distributions of pore size is mesoporous), high surface area (718 m(2)g(-1)), and proper surface functional groups (C-OH, C-O-S and COO-) of prepared microalga-based porous carbons. These results suggested that the microalgal biomass could be successfully applied in electrochemical storage of hydrogen.
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页数:7
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共 55 条
[11]   Electrochemical hydrogen storage capacity and optical properties of NiAl2O4/NiO nanocomposite synthesized by green method [J].
Gholami, Tahereh ;
Salavati-Niasari, Masoud ;
Varshoy, Shokufeh .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (08) :5235-5245
[12]   BIOSORPTION OF SOME TOXIC METALS FROM AQUEOUS SOLUTION USING NON-LIVING ALGAL CELLS OF CHLORELLA VULGARIS [J].
Goher, Mohamed E. ;
Abd El-Monem, Ahmed M. ;
Abdel-Satar, Amaal M. ;
Ali, Mohamed H. ;
Hussian, Abd-Ellatif M. ;
Napiorkowska-Krzebietke, Agnieszka .
JOURNAL OF ELEMENTOLOGY, 2016, 21 (03) :703-714
[13]   Sustainable microalgae for the simultaneous synthesis of carbon quantum dots for cellular imaging and porous carbon for CO2 capture [J].
Guo, Li-Ping ;
Zhang, Yan ;
Li, Wen-Cui .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 493 :257-264
[14]   Chlorella-derived activated carbon with hierarchical pore structure for energy storage materials and adsorbents [J].
Han, Joah ;
Lee, Kyubock ;
Choi, Min Sung ;
Park, Ho Seok ;
Kim, Woong ;
Roh, Kwang Chul .
CARBON LETTERS, 2019, 29 (02) :167-175
[15]   Electrochemical Study of Antioxidant Capacity of Gracilaria Pygmaea Macro-Algae Based on the Green Synthesis of Gold Nanoparticles: Assessment of Its Cytotoxic Effect on Four Cancer Cell Lines [J].
Hashkavayi, Ayemeh Bagheri ;
Hashemnia, Sedigheh ;
Osfouri, Shahriar ;
Zarei, Somayeh .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 166 (12) :B969-B977
[16]   Fabrication and electrochemical activity of Ni-attached carbon nanotube electrodes for hydrogen storage in alkali electrolyte [J].
Hsieh, Chien-Te ;
Chu, Yun-Wen ;
Lin, Jia-Yi .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (15) :3457-3464
[17]   Influence of oxygen treatment on electric double-layer capacitance of activated carbon fabrics [J].
Hsieh, CT ;
Teng, H .
CARBON, 2002, 40 (05) :667-674
[18]   Mechanism of Electrochemical Hydrogen Storage for α-Fe2O3 Particles as Anode Material for Aqueous Rechargeable Batteries [J].
Huo, Ge ;
Lu, Xuegang ;
Liang, Gongying .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (07) :H566-H569
[19]   Hydrogen: the energy source for the 21st century [J].
Johnston, B ;
Mayo, MC ;
Khare, A .
TECHNOVATION, 2005, 25 (06) :569-585
[20]   Towards the mechanism of electrochemical hydrogen storage in nanostructured carbon materials [J].
Jurewicz, K ;
Frackowiak, E ;
Béguin, F .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2004, 78 (07) :981-987