Highly Porous Carbon from Microalga,Chlorella Vulgaris, as an Electrochemical Hydrogen Storage Material

被引:13
作者
Seifi, Hooman [1 ]
Masoum, Saeed [1 ,2 ]
Hosseini Tafreshi, Seyed Ali [2 ]
Seifi, Soodabe [1 ]
Jafari, Seyed Mostafa [1 ]
机构
[1] Univ Kashan, Dept Analyt Chem, Fac Chem, Kashan, Iran
[2] Univ Kashan, Dept Cell & Mol Biol, Fac Chem, Kashan, Iran
关键词
Electrochemical hydrogen storage; Microalga; Chlorella vulgaris; Biomass; Porous carbon; Renewable energy; ACTIVATED CARBON; HIGH-PERFORMANCE; MICROALGAE; CAPACITY; GROWTH; ALGAE; SUPERCAPACITOR; CARBONIZATION; FABRICATION; ELECTRODES;
D O I
10.1149/1945-7111/abaf73
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Chlorella Vulgaris, as a well-known green microalga is considered as a reliable biomass source with vast biotechnological potential to produce various high-performance products. In the present study, porous carbon with a specific surface area was produced via a hydrothermal technique. The investigated materials were characterized by Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), energy-dispersive X-ray (EDX), Brunauer-Emmett-Teller (BET) and transmission electron microscopy (TEM). The electrochemical hydrogen storage (EHS) capacity of the product was investigated by a three-electrode system (chronopotentiometry) in 6 M KOH electrolyte. The microalga-based porous carbons showed a good electrochemical hydrogen storage capacity equal to 1040 mAh g(-1)(3.9 wt%) after 40 cycles. This great capacity principally is due to the porous structure (distributions of pore size is mesoporous), high surface area (718 m(2)g(-1)), and proper surface functional groups (C-OH, C-O-S and COO-) of prepared microalga-based porous carbons. These results suggested that the microalgal biomass could be successfully applied in electrochemical storage of hydrogen.
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页数:7
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