A Convenient Synthetic Route to Partial-Cone p-Carboxylatocalix[4]arenes

被引:1
|
作者
Fairbairn, Robyn E. [1 ]
Teat, Simon J. [2 ]
Gagnon, Kevin J. [2 ]
Dalgarno, Scott J. [1 ]
机构
[1] Heriot Watt Univ, Inst Chem Sci, Edinburgh, Midlothian, Scotland
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
关键词
p-Carboxylatocalix[4]arene; Supramolecular assemblies; METAL; ORGANIZATION; COMPLEXES; CAPSULES; SPHERES; DESIGN;
D O I
10.2533/chimia.2015.516
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
p-Carboxylatocalix[n]arenes have emerged as useful building blocks for the construction of a diverse range of supramolecular assemblies. A convenient route to a p-carboxylatocalix[4]arene that is locked in a partial-cone conformation is presented. The conformation gives the molecule markedly different topological directionality relative to those previously used in self- and metal-directed assembly studies.
引用
收藏
页码:516 / 519
页数:4
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