Aluminum doped zinc oxide sputtering targets obtained from nanostructured powders: Processing and application

被引:50
作者
Neves, Nuno [1 ,2 ,3 ]
Barros, Raquel [1 ,2 ,3 ]
Antunes, Elsa [1 ]
Calado, Joao [1 ]
Fortunato, Elvira [2 ,3 ]
Martins, Rodrigo [2 ,3 ]
Ferreira, Isabel [2 ,3 ]
机构
[1] Mat Avancados SA, INNOVNANO, P-3040570 Antanhol, Portugal
[2] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Ciencia Mat, CENIMAT 13N, P-2829516 Caparica, Portugal
[3] CEMOP UNINOVA, P-2829516 Caparica, Portugal
关键词
Aluminum doped zinc oxide (AZO); Electrical conductivity; Sintering; Final microstructure; Films; THIN-FILMS; GRAIN-GROWTH; TRANSPARENT; AL; NANOCRYSTALLINE; DENSIFICATION; TEMPERATURE;
D O I
10.1016/j.jeurceramsoc.2012.08.007
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This work reports the production of ceramic targets based on nanostructured Al-doped ZnO (AZO) powders for sputtering applications. The nanostructured powder is obtained by a new patented process based on the detonation of an emulsion containing both Zn and Al metal precursors in the final proportion of 98:2 wt% (ZnO:Al2O3), through which the Al contains is highly uniform distributed over ZnO. Due to the nanostructured powder characteristics, the targets can be sintered at substantially lower temperatures (1150-1250 degrees C) by conventional sintering, contributing to production costs reduction of ceramic targets and consequently the costs of photovoltaic and displays industries. Electrical resistivity values around 3.0-7.0 x 10(-3) Omega cm have been obtained depending on final microstructure of the targets. The electro-optical properties of the films produced at room temperature with thicknesses around 360 nm, besides being highly uniform exhibit a resistivity of about 1 x 10(-3) Omega cm and a transmittance in the visible range above 90%. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4381 / 4391
页数:11
相关论文
共 46 条
[1]   Elaboration and characterization of Si(n)/PS/ZnO(n) structure obtained by rf-magnetron sputtering from aerogel nanopowder target material [J].
Alaya, A. ;
Nouiri, M. ;
Ben Ayadi, Z. ;
Djessas, K. ;
Khirouni, K. ;
El Mir, L. .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2009, 159-60 :2-5
[2]   The properties of aluminum-doped zinc oxide thin films prepared by rf-magnetron sputtering from nanopowder targets [J].
Ben Ayadi, Z. ;
El Mir, L. ;
Djessas, K. ;
Alaya, S. .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2008, 28 (5-6) :613-617
[3]   Highly sensitive ZnO ozone detectors at room temperature [J].
Bender, M ;
Fortunato, E ;
Nunes, P ;
Ferreira, I ;
Marques, A ;
Martins, R ;
Katsarakis, N ;
Cimalla, V ;
Kiriakidis, G .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2003, 42 (4B) :L435-L437
[4]   High quality Al-doped ZnO thin films deposited using targets prepared by chemical coprecipitation [J].
Cai, L. ;
Jiang, G. ;
Zhu, C. ;
Wang, D. .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2009, 206 (07) :1461-1464
[5]  
Calado J M, 2009, Patent No. [WO 2009144665, 2009144665]
[6]   Role of annealing environment on the performances of large area ITO films produced by rf magnetron sputtering [J].
Canhola, P ;
Martins, N ;
Raniero, L ;
Pereira, S ;
Fortunato, E ;
Ferreira, I ;
Martins, R .
THIN SOLID FILMS, 2005, 487 (1-2) :271-276
[7]   Preparation and characterization of n-type conductive (Al, Co) co-doped ZnO thin films deposited by sputtering from aerogel nanopowders [J].
El Mir, L. ;
Ben Ayadi, Z. ;
Saadoun, M. ;
Djessas, K. ;
von Bardeleben, H. J. ;
Alaya, S. .
APPLIED SURFACE SCIENCE, 2007, 254 (02) :570-573
[8]   Analysis of nanocrystalline and microcrystalline ZnO sintering using master sintering curves [J].
Ewsuk, Kevin G. ;
Ellerby, Donald T. ;
DiAntonio, Christopher B. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (06) :2003-2009
[9]   MOSS-BURSTEIN EFFECT IN N TYPE INSB CRYSTALS DOPED WITH SELENIUM AND TELLURIUM [J].
FILIPCHE.AS ;
NASLEDOV, DN ;
RADAIKIN.LN ;
RATNER, II .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1972, 14 (01) :71-75
[10]   Highly stable transparent and conducting gallium-doped zinc oxide thin films for photovoltaic applications [J].
Fortunato, E. ;
Raniero, L. ;
Silva, L. ;
Goncalves, A. ;
Pimentel, A. ;
Barquinha, P. ;
Aguas, H. ;
Pereira, L. ;
Goncalves, G. ;
Ferreira, I. ;
Elangovan, E. ;
Martins, R. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (12) :1605-1610