Tandem oxidation processes using manganese dioxide: Discovery, applications, and current studies

被引：302
作者：
Taylor, RJK [1 ]
Reid, M [1 ]
Foot, J [1 ]
Raw, SA [1 ]
机构：
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2005年 / 38卷 / 11期
关键词：
D O I：
10.1021/ar050113t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One-pot processes in which alcohol oxidations are combined with further elaboration of the carbonyl intermediate are reviewed. Sequential processes are briefly discussed, but most attention is centered on tandem processes; that is, oxidations carried out in the presence of a nucleophilic trapping agent, rather than those in which the trapping agent is added after the oxidation is complete. As part of this Account, a comprehensive review of the discovery of tandem oxidation processes (TOP) will be given together with applications in alkene-forming reactions, cyclopropanations, and imine, oxime, amine, and heterocycle formation.
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页码：851 / 869
页数：19
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