Preparation of transparent PMMA/Fe(IO3)3 nanocomposite films from microemulsion polymerization

被引:4
作者
Houf, Latifa [1 ]
Mugnier, Yannick [1 ]
Rouxel, Didier [2 ]
Le Dantec, Ronan [1 ]
Badie, Laurent [2 ]
Vincent, Brice [2 ]
Coustal, Cecile [3 ]
Beauquis, Sandrine [1 ]
Thevenet, Charlotte [3 ]
Galez, Christine [1 ]
机构
[1] Univ Savoie, SYMME, F-74944 Annecy Le Vieux, France
[2] Univ Nancy 1, Inst Jean Lamour, CNRS, UMR 7198,Dept P2M, F-54506 Vandoeuvre Les Nancy, France
[3] PLASTIPOLIS, F-01115 Oyonnax, France
关键词
colloids; crystallization; nanoparticles; nanowires and nanocrystals; nanostructured polymers; dielectric properties; 2ND-HARMONIC GENERATION; IODATE NANOCRYSTALS; W/O MICROEMULSIONS; OPTICAL-PROPERTIES; NANOPARTICLES; SCATTERING;
D O I
10.1002/app.39271
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polymethyl methacrylate (PMMA)/Fe(IO3)(3) nanocomposite thin films are obtained by in situ particle generation in microemulsions and subsequent photopolymerization of a mixture containing methyl methacrylate, trimethylolpropane triacrylate, and crystallized iron iodate (Fe(IO3)(3)) nanorods. Hyper-Rayleigh scattering measurements combined with X-ray diffraction, transmission electron microscopy, and dynamic light scattering are first used to probe in situ the crystallization kinetics of iron iodate nanorods in water-in-oil microemulsions prepared with methyl methacrylate as the oil phase and marlophen NP12 as a surfactant. laser Doppler vibrometry, and Brillouin spectroscopy. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1203-1211, 2013
引用
收藏
页码:1203 / 1211
页数:9
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