Poly[2-(acetoacetoxy)ethyl methacrylate]-based hybrid micelles

被引：0
|
作者：
Krasia, Theodora [1 ]
Schlaad, Helmut [1 ]
机构：
[1] Max Planck Inst Colloids & Interfaces, Colloid Dept, D-14476 Potsdam, Germany
来源：
METAL-CONTAINING AND METALLOSUPRAMOLECULAR POLYMERS AND MATERIALS | 2006年 / 928卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Block copolymers based on n-butyl methacrylate (BMA) and 2-(acetoacetoxy)ethyl methacrylate (AEMA), a commercially available monomer bearing a P-dicarbonyl ligand, are used for the solubilization of metal ions (Fe3+, Co2+, Pd2+) in organic media. Stable colloidal dispersions of inverse hybrid micelles can be obtained in cyclohexane. Even though not soluble in the continuous phase, the metal ions are evenly distributed among aggregates. Due to their narrow size distribution, the hybrid micelles tend to form ordered domains when being deposited on a solid substrate.
引用
收藏
页码：157 / 167
页数：11
相关论文
共 50 条
  • [1] Superhelices of poly[2-(acetoacetoxy)ethyl methacrylate]
    Schlaad, H
    Krasia, T
    Antonietti, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (36) : 11307 - 11310
  • [2] POLY 459-Aggregation behavior of block copolymers based on 2-(acetoacetoxy)ethyl methacrylate
    Krasia-Christoforou, Theodora
    Sigel, Reinhard
    Schlaad, Helmut
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 232
  • [3] Micellization Behavior of Poly(n-butyl methacrylate)-block-poly(2-(acetoacetoxy)ethyl methacrylate)
    Sigel, Reinhard
    Krasia-Christoforou, Theodora
    Below, Ines
    Schlaad, Helmut
    MACROMOLECULES, 2009, 42 (12) : 4257 - 4261
  • [4] Colloidal properties of block copolymers based on 2-(acetoacetoxy)ethyl methacrylate: Organic-inorganic hybrid materials
    Krasia, T
    Schlaad, H
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U451 - U451
  • [5] Ammonia gas-sensing characteristics of fluorescence-based poly(2-(acetoacetoxy)ethyl methacrylate) thin films
    He, Jing
    Zhang, Tong-Yi
    Chen, Guohua
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 373 : 94 - 101
  • [6] Copolyperoxides of 2-(acetoacetoxy)ethyl methacrylate with methyl methacrylate and styrene; Synthesis, characterization, thermal analysis, and reactivity ratios
    Pal, Sunirmal
    Banoth, Balaraju
    Rahithya, Goli
    Dhawan, Ashish
    De, Priyadarsi
    POLYMER, 2012, 53 (13) : 2583 - 2590
  • [7] Controlled synthesis of homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate via RAFT radical polymerisation
    Krasia, T
    Soula, R
    Börner, HG
    Schlaad, H
    CHEMICAL COMMUNICATIONS, 2003, (04) : 538 - 539
  • [8] A superparamagnetic metallopolymer using tailor-made poly [2-(acetoacetoxy)ethyl methacrylate] bearing pendant β-keto ester functionality
    Mandal, Prithwiraj
    Banerjee, Sovan Lal
    Bhattacharya, Koushik
    Singha, Nikhil K.
    EUROPEAN POLYMER JOURNAL, 2018, 103 : 31 - 39
  • [9] Intravenous fate of poly(2-(dimethylamino)ethyl methacrylate)-based polyplexes
    Verbaan, F
    van Dam, I
    Takakura, Y
    Hashida, M
    Hennink, W
    Storm, G
    Oussoren, C
    EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES, 2003, 20 (4-5) : 419 - 427
  • [10] Studies on core–shell structural nano-micelles based on star block copolymer of poly(lactide) and poly(2-(dimethylamino)ethyl methacrylate)
    Caihua Ni
    Guangjun Zhu
    Changping Zhu
    Bolong Yao
    D. N. T. Kumar
    Colloid and Polymer Science, 2010, 288 : 1193 - 1200
12345