Palladium-Catalyzed Highly Regioselective [3+2] Cycloaddition Reactions of Alkylidenecyclopropa[b]naphthalenes with Alkenes or Alkynes: An Efficient Synthesis of 1(3)-Alkylidene-2,3-dihydro-1H-benzo[f]indenes and 1-Alkylidene-1H-benzo[f]indenes

被引：23

作者：

Chen, Wanli ^{[2
]}

Cao, Jian ^{[1
]}

Huang, Xian ^{[1
,3
]}

机构：

[1] Zhejiang Univ Technol, Ctr Anal & Measurement, Hangzhou 310014, Zhejiang, Peoples R China

[2] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 24期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1021/ol8023083

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first palladium-catalyzed highly regioselective [3 + 2] cycloaddition reactions of alkylidenecyclopropa[b]naphthalenes 1 with alkenes or alkynes is presented, providing an efficient method for the synthesis of 1(3)-alkylidene-2,3-dihydro-1H-benzo[f]indenes or 1-alkylidene-1H-benzo[f]indenes under mild conditions.

引用

页码：5537 / 5540

页数：4

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