Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation

被引：48

作者：

Barker, Ian A. ^{[1
]}

Dove, Andrew P. ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

EPSILON-CAPROLACTONE; ACTIVATED MONOMER; ORGANOCATALYSTS; GUANIDINE; AMIDINE; LACTIDE;

D O I：

10.1039/c2cc38114a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(delta-valerolactone)-b-poly(L-lactide)-b-poly(delta-valerolactone) in a 'one-pot' reaction.

引用

页码：1205 / 1207

页数：3

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